期刊
ACS CATALYSIS
卷 8, 期 6, 页码 4772-4776出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b00900
关键词
hydroboration; deoxygenation; boronate esters; carboxylic acid; catalysis
资金
- SERB New Delhi [EMR/2016/002517]
- DAE
- NISER
- DST
- SERB
An efficient deoxygenative hydroboration of carboxylic acids to alkyl boronate esters under mild reaction condition is reported. Both aromatic and aliphatic carboxylic acids exhibited excellent reactivities with minimal catalyst load of 0.1 mol % and reactions occurred under neat conditions. This catalytic transformation selectively provides alkyl boronate esters, which can be conveniently hydrolyzed to obtain the corresponding alcohols. Remarkably, this reduction reaction proceeds with the liberation of molecular hydrogen.
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