期刊
CHEMICAL SCIENCE
卷 9, 期 32, 页码 6647-6652出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc01747f
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资金
- EPSRC
Aryl dialkyl amines, valuable subunits of a wide range of effect chemicals, are accessed by intramolecular amination of aromatic C-H bonds employing UV photolysis of N-chloroamines. The reactions show good functional group tolerance and allow access to a range of fused and bridged polycyclic structures. The homogeneous reaction conditions allow for the one-pot conversion of secondary amines to their arylated derivatives. Experimental and theoretical evidence supports the involvement of electrophilic aminium radicals which react via direct ortho-attack on the arene.
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