Linking defects, hierarchical porosity generation and desalination performance in metal–organic frameworks

Ordered macro-microporous metal-organic framework single crystals

(2018) Kui Shen et al.   SCIENCE

Defect engineering of Mn-based MOFs with rod-shaped building units by organic linker fragmentation

(2017) Doufeng Wu et al.   INORGANICA CHIMICA ACTA

Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study

(2017) Cesare Atzori et al.   Journal of Physical Chemistry C

Metal–Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal–Organic Framework

(2017) Matthew J. Cliffe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of MOF surface defects on the microscopic structure of MOF/polymer interfaces: A computational study of the ZIF-8/PIMs systems

(2017) Rocio Semino et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Gel-based morphological design of zirconium metal–organic frameworks

(2017) Bart Bueken et al.   Chemical Science

Aluminum fumarate-based metal organic frameworks with tremella-like structure as ultrafast and stable anode for lithium-ion batteries

(2017) Yan Wang et al.   Nano Energy

A Drying-Free, Water-Based Process for Fabricating Mixed-Matrix Membranes with Outstanding Pervaporation Performance

(2016) Yu-Heng Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Ultrathin, Continuous Metal-Organic Framework Membranes on Flexible Polymer Substrates

(2016) Jingwei Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing the correlations between the defects in metal–organic frameworks and their catalytic activity by an epoxide ring-opening reaction

(2016) Yangyang Liu et al.   CHEMICAL COMMUNICATIONS

Rational construction of defects in a metal–organic framework for highly efficient adsorption and separation of dyes

(2016) Keke Wang et al.   CHEMICAL ENGINEERING JOURNAL

Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis

(2016) Greig C. Shearer et al.   CHEMISTRY OF MATERIALS

Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66

(2016) Greig C. Shearer et al.   CHEMISTRY OF MATERIALS

Defect engineering of UiO-66 for CO2 and H2O uptake – a combined experimental and simulation study

(2016) Weibin Liang et al.   DALTON TRANSACTIONS

Defects in metal–organic frameworks: a compromise between adsorption and stability?

(2016) A. W. Thornton et al.   DALTON TRANSACTIONS

Origin of highly active metal–organic framework catalysts: defects? Defects!

(2016) J. Canivet et al.   DALTON TRANSACTIONS

Stability of an Al-Fumarate MOF and Its Potential for CO2 Capture from Wet Stream

(2016) Juliana A. Coelho et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Urea Hydrolysis Rate in Soil Toposequences as Influenced by pH, Carbon, Nitrogen, and Soluble Metals

(2016) Kristin A. Fisher et al.   JOURNAL OF ENVIRONMENTAL QUALITY

CaO-ZrO 2 nanocomposite oxide prepared by urea hydrolysis method as heterogeneous base catalyst for synthesis of chromene analogues

(2016) Sagnika Pradhan et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Interplay between defects, disorder and flexibility in metal-organic frameworks

(2016) Thomas D. Bennett et al.   Nature Chemistry

Shape selective properties of the Al-fumarate metal–organic framework in the adsorption and separation of n-alkanes, iso-alkanes, cyclo-alkanes and aromatic hydrocarbons

(2016) Belgin Bozbiyik et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Mechanical energy storage performance of an aluminum fumarate metal–organic framework

(2016) Pascal G. Yot et al.   Chemical Science

Evaluation of Brønsted acidity and proton topology in Zr- and Hf-based metal–organic frameworks using potentiometric acid–base titration

(2016) Rachel C. Klet et al.   Journal of Materials Chemistry A

The Structure of the Aluminum Fumarate Metal-Organic Framework A520

(2015) Elsa Alvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Defect-Engineered Metal-Organic Frameworks

(2015) Zhenlan Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption

(2015) Weibin Liang et al.   CHEMICAL COMMUNICATIONS

Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks

(2015) Oleksii V. Gutov et al.   INORGANIC CHEMISTRY

Defects in Metal–Organic Frameworks: Challenge or Opportunity?

(2015) David S. Sholl et al.   Journal of Physical Chemistry Letters

Destruction of chemical warfare agents using metal–organic frameworks

(2015) Joseph E. Mondloch et al.   NATURE MATERIALS

Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework

(2015) Matthew J. Cliffe et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties

(2014) Olesia Kozachuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Complexity in Metal–Organic Frameworks: Simultaneous Modification of Open Metal Sites and Hierarchical Porosity by Systematic Doping with Defective Linkers

(2014) Zhenlan Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)

(2013) Frederik Vermoortele et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A review of fine structures of nanoporous materials as evidenced by microscopic methods

(2013) Zheng Liu et al.   Microscopy

Reactions of VX, GD, and HD with Zr(OH)4: Near Instantaneous Decontamination of VX

(2012) Teresa J. Bandosz et al.   Journal of Physical Chemistry C

Adsorption of Ammonia by Sulfuric Acid Treated Zirconium Hydroxide

(2012) T. Grant Glover et al.   LANGMUIR

Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation

(2012) Guang Lu et al.   Nature Chemistry

Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory

(2011) Loredana Valenzano et al.   CHEMISTRY OF MATERIALS

Highly Dispersed Palladium(II) in a Defective Metal–Organic Framework: Application to C–H Activation and Functionalization

(2011) Tae-Hong Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities

(2010) Omar K. Farha et al.   Nature Chemistry

Free Carboxylate Stretching Modes

(2008) Jos Oomens et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Metal–organic framework MOF-5 prepared by microwave heating: Factors to be considered

(2008) Jung-Sik Choi et al.   MICROPOROUS AND MESOPOROUS MATERIALS