期刊
CHEMICAL SCIENCE
卷 9, 期 27, 页码 5883-5889出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc01818a
关键词
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资金
- ERC (European Research Council) [334840]
- NCCR Chemical Biology (Swiss Science National Foundation)
- EPFL
- European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie [701885]
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers. The redox properties of the dyes were determined by both cyclic voltammetry and computation and covered an existing gap in the oxidation potential of photoredox organocatalysts.
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