期刊
TETRAHEDRON LETTERS
卷 59, 期 3, 页码 203-215出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.12.034
关键词
Aminotrifluoromethylation; Azidotrifluoromethylation; Alkene; Copper catalysis; Photoredox catalysis
资金
- National Natural Science Foundation of China [21722203, 21572096]
- Shenzhen special funds for the development of biomedicine, Internet, new energy, and new material industries [JCYJ20170412152435366, JCYJ20170307105638498]
Trifluoromethylation of alkenes has long been the interest of synthetic chemists. It is not only because of the great importance of F-containing compounds, but also on account of the pleasure of cracking the challenges in methodology development in this field. In particular, amino- and azidotrifluoromethylation of alkenes have recently been developing in a fast speed. This digest mainly deals with this advancement in racemic copper- and photocatalyzed amino- and azidotrifluoromethylation of alkenes while giving special highlight on our recent breakthrough on the copper-catalyzed asymmetric aminotrifluoromethylation reaction. (C) 2017 Elsevier Ltd. All rights reserved.
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