期刊
SYNLETT
卷 29, 期 3, 页码 257-265出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591749
关键词
diamines; diazidation; electrochemistry; electrocatalysis; radicals
资金
- Cornell University
- Atkinson Center for a Sustainable Future
Vicinal diamines are highly prevalent structural motifs in therapeutic agents, bioactive natural products, and molecular catalysts. However, there are currently few unified methodological approaches for making these pertinent synthetic building blocks. This Synpacts article provides an overview of selected landmark developments in the area of olefin diamination. In particular, we highlight our recent contribution on the electrocatalytic diazidation of olefins as a general, selective, and sustainable method for the synthesis of vicinal diamines. 1 Introduction 2 Background: Intermolecular Diamination of Olefins 3 Background: Intermolecular Diazidation of Olefins 4 Electrocatalytic Diazidation of Olefins
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