4.5 Article

Effect of Sn doping on structural, mechanical, optical and electrical properties of ZnO nanoarrays prepared by sol-gel and hydrothermal processEffect of Sn doping on structural, mechanical, optical and electrical properties of ZnO nanoarrays prepared by sol-gel and hydrothermal process

期刊

SUPERLATTICES AND MICROSTRUCTURES
卷 117, 期 -, 页码 342-350

出版社

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.spmi.2018.03.061

关键词

Hydrothermal; Wurtzite; Zinc oxide; Nanorods; XRD; Stress; Strain; Young's modulus

资金

  1. Department of Science and Technology [SR/FTP/PS-184/2012]
  2. SERB [SERB/F/5439/2013-14]
  3. Faculty Research Scheme-FRS [(54)/2103-2014/APH]
  4. Indian Institute of Technology (Indian School of Mines), Dhanbad, India

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Undoped and Sn doped Zinc oxide nanorods were prepared by two step process: initially growth of seed layers by sol-gel spin coating technique and then zinc oxide nanorods by hydrothermal process using the precursors zinc nitrate hexahydrate, hexamine and tin chloride. The effects on the electrical, optical, mechanical and structural properties for various Sn concentrations were studied. The crystalline phase determination from X-ray diffraction (XRD) confirms that Sn doped ZnO nanorods have hexagonal wurtzite structure. The variations of stress and strain with different doping concentration of Sn in ZnO nanorods were studied. The doping effect on electrical properties and optical bandgap is estimated by current voltage characteristics and absorbance spectra respectively. The surface morphology was studied with field emission scanning electron microscope (FESEM), which shows that the formation of hexagonal nanorods arrays with increasing Sn concentration. The calculated value of Young's modulus of elasticity (Y) for all the samples remains same. These results can be used in optoelectronic devices. (C) 2018 Elsevier Ltd. All rights reserved.

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