期刊
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
卷 44, 期 4, 页码 272-283出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070328418040085
关键词
redox active ligands; o-quinones; redox isomerism; cobalt
The key regularities of redox isomerism of six-coordinate bis-semiquinonato cobalt complexes in the crystalline phase are considered. The factors determining the temperature of transition between the redox isomers of various cobalt complexes (mononuclear and binuclear complexes, coordination polymers) were described. The transition parameters were shown to depend not only on the electronic and spatial structure of the ligands in a particular complex, but also on the crystal structure of the complex and intermolecular interactions in the lattice.
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