期刊
RESOURCES CONSERVATION AND RECYCLING
卷 129, 期 -, 页码 135-142出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.resconrec.2017.10.021
关键词
Recycling; Spent lithium ion battery; Nickel-manganese-cobalt oxide; Bifunctional air electrode
资金
- Thousands Youth Talents Project of China
- Natural Science Foundation of China [51704122]
- Natural Science Foundation of Hubei Province, China [2015CFA133]
Spent lithium ion batteries are potential environmental hazards and if not re-cycled waste natural resources. One of the difficulties for recovery is the recycling cost high and restricting the economic drivers. In this research, a process is developed to directly reuse nickel-manganese-cobalt oxides from spent lithium ion batteries to prepare air electrodes based on a simple thermal treatment method. 100% value metals (cobalt, nickel and manganese) were regenerated from the cathode. By heated at 600 degrees C, the Ni-Co-Mn oxides experienced a significant phase change from an alpha-NaFeO2-type structure to spinel structure. Electrochemical tests revealed that the regenerated nickel-manganese-cobalt oxides exhibited remarkable bifunctional catalytic activities towards the oxygen evolution and oxygen reduction reactions in aqueous KOH electrolyte. The nickel-manganese-cobalt oxide powders were applied in an air battery, the energy efficiency was 75% at a current density of 10 mA cm(-2), which was better than commercal zinc-air batteries.
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