期刊
PROGRESS IN ORGANIC COATINGS
卷 122, 期 -, 页码 10-18出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2018.05.008
关键词
UV-curing; Waterborne polyurethane; Kinetics; FT-IR; Photo-DSC
资金
- Natural Science Foundation of Jiangsu Province [BK20161362, BK20161264]
- 333 High-Level Personnel Training Project of Jiangsu Province [BRA2016142]
- Zhenjiang College Scientific Research Team [ZJCKYD2017023]
Environmentally friendly waterborne polyurethane-acrylate (WPUA) oligomers and ultraviolet curing WPUA films (UV-WPUA) were prepared. The thermal stability, solvent-resistance and mechanical properties of the films were investigated. FT-IR and photo-DSC methods were used to investigate the photopolymerization kinetics of the UV-WPUA films. The results showed that UV-curing films offered the optimum combination of properties when the polyether polyol (NJ-330), isophorone diisocyanate (IPDI), hydroxyethyl methyl acrylate (HEMA) and dimethylolbutanoic acid (DMBA) were used as the raw materials and the mass ratio of oligomer: monomer butyl acrylate (BA): photoinitiator was fixed at 66:30:4. Reaction kinetics of different photoinitiators systems were calculated by Kissinger equation and Crane equation, thus providing a theoretical guidance for the optimization of diluent and photoinitiator in UV-curing coating industry.
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