期刊
PROGRESS IN ORGANIC COATINGS
卷 120, 期 -, 页码 88-99出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2018.01.019
关键词
Polyurethane; Ammonium polyphosphate; Flame retardancy; Mechanical property; Curing behavior; Solvent-free
资金
- National Natural Science Foundation of China [21576172, 51273128]
To simultaneously improve the compatibility, flame retardancy and mechanical properties of ammonium polyphosphate (APP) based polyurethane, an efficient and facile strategy was developed, in which hydroxyl-functionalized APP (HAPP) was synthesized through ion-exchange reaction between APP and 3-aminopropanol, and then utilized as a multiple-function excipient for solvent-free two-component polyurethane (2K-PU) by chemical cross-linking. The curing behavior, mechanical and flame-retardant performances of HAPP cured 2K-PU, designating as 2K-PU/HAPP, were elaborately evaluated. Cone calorimeter results indicated that the conjugation of 15 wt% HAPP into 2K-PU significantly reduced the peak heat release rate (PHRR), total heat release (THR) and total smoke production (TSP) by 68.7%, 42.8% and 9.3%, respectively. Intriguingly, mechanical tests illustrated that the chemical incorporation of HAPP definitely improved the tensile strength of 2K-PU/HAPP while well-maintained the elongation at break, highlighting its attractive potential for industrial application. In addition, a flame-retardant mechanism for 2K-PU/HAPP was proposed. All aforementioned results distinctly demonstrate a feasible yet promising paradigm for fabricating APP-containing polyurethane.
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