4.5 Article

Comparison of liquid and liquid-gas phase plasma reactors for discoloration of azo dyes: Analysis of degradation products

期刊

PLASMA PROCESSES AND POLYMERS
卷 15, 期 6, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppap.201700178

关键词

azo textile dyes; DC discharges; dielectric barrier discharges; discoloration; HPLC-MS analyses

资金

  1. Ministry of Education, Science and Technological Development of the Republic of Serbia [OI 171034, OI 172030]
  2. Czech Ministry of Education, Youth and Sports [COST LC14014]

向作者/读者索取更多资源

Three plasma systems are used for decomposition of two organic textile dyes. The highest discoloration efficiency over 90% is reached in the water falling film DBD when maximal energy of 270 and 450kJL(-1) is applied into Reactive Yellow 125 and Direct Red 79 dye solutions, respectively. Decomposition of the dye molecules is confirmed by concentration decreases in dye chromatograms. Similar degradation products are identified in the positive diaphragm discharge and water falling film DBD. In the negative diaphragm discharge, different products are formed due to electrochemical reactions on the anode. Substitution of halogens, hydrogen addition on the azo group and the cleavage of the azo group itself are the main mechanisms contributing to the destruction of the dye molecule in the compared plasma systems.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Activation of Oxone® with plasma deposited mixed cobalt and alumina oxide for the dye degradation

Marija Ajdukovic, Stevan Stojadinovic, Sanja Marinovic, Aleksandra Milutinovic-Nikolic, Biljana Dojcinovic, Predrag Bankovic

APPLIED SURFACE SCIENCE (2020)

Article Biochemistry & Molecular Biology

Antitumor activity of organoruthenium complexes with chelate aromatic ligands, derived from 1,10-phenantroline: Synthesis and biological activity

Aleksandar Savic, Nevenka Gligorijevic, Sandra Arandelovic, Biljana Dojcinovic, Anna M. Kaczmarek, Sinisa Radulovic, Rik Van Deun, Kristof Van Hecke

JOURNAL OF INORGANIC BIOCHEMISTRY (2020)

Article Materials Science, Coatings & Films

Effects of high thermal loads produced by interaction of accelerated plasma with steel surfaces (100Cr6, 16MnCr5, 42CrMo4)

Nora Trklja Boca, Zarko Z. Miskovic, Radivoje M. Mitrovic, Bratislav M. Obradovic, Milorad M. Kuraica

Summary: The magnetoplasma compressor (MPC) is used for treatment and alloying of steel samples, with a high-speed plasma flow melting the surface and creating a new thin layer, resulting in a significant improvement of hardness after treatment within MPC.

SURFACE & COATINGS TECHNOLOGY (2021)

Article Materials Science, Textiles

Enhanced Antimicrobial Activity of Atmospheric Pressure Plasma Treated and Aged Cotton Fibers

Ana D. Kramar, Bratislav M. Obradovic, Sonja Schiehser, Antje Potthast, Milorad M. Kuraica, Mirjana M. Kostic

Summary: Plasma pretreatment of raw cotton fibers combined with silver sorption enhances the antimicrobial activity of fabrics, with significantly higher silver sorption observed when conducted seven days after plasma treatment, highlighting the importance of plasma aging as a factor in fibers' functionalization.

JOURNAL OF NATURAL FIBERS (2022)

Article Chemistry, Physical

Iso- and Anisotropic Etching of Micro Nanofibrillated Cellulose Films by Sequential Oxygen and Nitrogen Gas Plasma Exposure for Tunable Wettability on Crystalline and Amorphous Regions

Katarina Dimic-Misic, Mirjana Kostic, Bratislav Obradovic, Milorad Kuraica, Ana Kramar, Monireh Imani, Patrick Gane

Summary: The cellulose films obtained from refined pulp with different enzymatic pretreatment digestion times were exposed to gas plasma, resulting in surface chemical and morphological changes affecting mechanical and surface properties. Single and dual exposure to oxygen and nitrogen plasma showed differing effects on the roughness, nanostructural and chemical changes, and wettability of the cellulose film. Oxygen plasma induced greater morphological change, while nitrogen plasma contributed more to chemical modification of the film surface.

MATERIALS (2021)

Article Chemistry, Physical

Chitosan Nanoparticles Functionalized Viscose Fabrics as Potentially Durable Antibacterial Medical Textiles

Matea Korica, Zdenka Persin, Lidija Fras Zemljic, Katarina Mihajlovski, Biljana Dojcinovic, Snezana Trifunovic, Alenka Vesel, Tanja Nikolic, Mirjana M. Kostic

Summary: This research introduced two pretreatments of viscose fabrics, oxidizing with TEMPO and coating with TOCN, to enhance the washing durability of antibacterial properties of chitosan nanoparticles functionalized fabrics. The pretreatments improved the antimicrobial activity against S. aureus even after five washing cycles and preserved antibacterial activity against E. coli with NCS + Zn functionalized pretreated viscose fabrics after one washing cycle.

MATERIALS (2021)

Article Food Science & Technology

Rosemary Essential Oils as a Promising Source of Bioactive Compounds: Chemical Composition, Thermal Properties, Biological Activity, and Gastronomical Perspectives

Darko Micic, Sasa Durovic, Pavel Riabov, Ana Tomic, Olja Sovljanski, Snezana Filip, Tomislav Tosti, Biljana Dojcinovic, Rade Bozovic, Dusan Jovanovic, Stevan Blagojevic

Summary: Rosemary is a widely cultivated plant used mainly for essential oils and spice, with diverse composition affecting quality, biological activity, and thermal properties. Essential oils from Serbia and Russia have different chemical compositions and properties, with Russian oil showing higher antimicrobial activity and Serbian oil exhibiting better antioxidant performance during frying. This could potentially impact the use of these oils as antioxidant agents for extending food shelf life or as antimicrobial agents.
Review Physics, Applied

Low-temperature plasmas in contact with liquids-a review of recent progress and challenges

Vesna V. Kovacevic, Goran B. Sretenovic, Bratislav M. Obradovic, Milorad M. Kuraica

Summary: The article reviews recent progress and insights in the study of low-temperature plasmas in contact with liquids at atmospheric pressure. It focuses on the breakdown mechanisms in discharges in contact with liquid, the specificities of plasma jets impinging on the liquid surface, and discharge generation with a high overvoltage. The article also covers innovative approaches in the generation of plasma in contact with liquids, as well as novel phenomena detected by imaging techniques and measurement of discharge parameters.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2022)

Article Physics, Fluids & Plasmas

Experimental study of gas flow rate influence on a dielectric barrier discharge in helium

Sasa S. Ivkovic, Nikola Cvetanovic, Bratislav M. Obradovic

Summary: A systematic study was conducted on the influence of gas flow rate on helium dielectric barrier discharge. The study focused on the relationship between gas flow rate and impurity level, as well as the consequent changes in discharge operation. The results showed a non-linear decrease in impurity concentration with increasing gas flow rate. Changes in electrical properties, such as breakdown voltage and current density, were observed with the gas flow. The study also revealed a change in excitation mechanism with variation in gas flow. The decrease in impurities was found to be the main mechanism behind the changes in discharge behavior.

PLASMA SOURCES SCIENCE & TECHNOLOGY (2022)

Article Polymer Science

Obtaining Medical Textiles Based on Viscose and Chitosan/Zinc Nanoparticles with Improved Antibacterial Properties by Using a Dielectric Barrier Discharge

Matea D. Korica, Ana Kramar, Zdenka Persin Fratnik, Bratislav Obradovic, Milorad M. Kuraica, Biljana Dojcinovic, Lidija Fras Zemljic, Mirjana Kostic

Summary: This study aimed to improve the antibacterial properties and washing durability of viscose textiles by using nonthermal gas plasma and functional coatings. The viscose fabric was modified with chitosan/zinc nanoparticles to enhance its functional groups for attachment of the coatings. The results showed that the plasma modification contributed to improved adsorption and antibacterial properties of the functionalized fabrics, making them suitable for high-value-added medical textiles.

POLYMERS (2022)

Article Green & Sustainable Science & Technology

Plasma Treatment as a Sustainable Method for Enhancing the Wettability of Jute Fabrics

Aleksandra Ivanovska, Marija Milosevic, Bratislav Obradovic, Zorica Svircev, Mirjana Kostic

Summary: In this study, raw jute fabric was treated with atmospheric pressure dielectric barrier discharge to improve its wettability. The changes in surface chemistry and morphology of the fabric were evaluated using spectroscopy and microscopy. The results showed that the plasma treatment enhanced the wettability of the fabric by altering its surface chemistry and morphology. The treated fabric could be utilized as a water-binding polysaccharide support for the growth of cyanobacterial biocrusts.

SUSTAINABILITY (2023)

Article Optics

Features of electric field distribution along helium atmospheric plasma jet in stepwise propagation mode of guided streamer

M. E. Pinchuk, G. B. Sretenovic, N. Cvetanovic, A. A. Dyachenko, B. M. Obradovic, O. M. Stepanova

Summary: The non-uniform distribution of electric field in an atmospheric pressure helium plasma jet was determined using the Stark spectroscopy technique. The jet was generated by tailoring applied voltage pulses and oscillations, allowing the guided streamer to propagate stepwise. The electric field distribution along the jet reflects the dynamics of the streamer propagation, with field weakening during stagnation and field strengthening during subsequent voltage fronts, accelerating the guided streamer.

EUROPEAN PHYSICAL JOURNAL D (2023)

Article Chemistry, Multidisciplinary

Self-Heating Flower-like Nanoconstructs with Limited Incorporation of Yttrium in Maghemite: Effect of Chemical Composition on Heating Efficiency, Cytotoxicity and Genotoxicity

Milos Ognjanovic, Zeljko Jacimovic, Milica Kosovic-Perutovic, Irina Besu Zizak, Tatjana Stanojkovic, Zeljko Zizak, Biljana Dojcinovic, Dalibor M. Stankovic, Bratislav Antic

Summary: Partial cation substitution can change the physical properties of compounds, and in this study, yttrium-substituted iron oxide nanoconstructs (YIONs) were prepared. The Y3+ substitution in maghemite (γ-Fe2O3) crystal structures was limited to 1.5%. The YIONs showed excellent heating efficiency and low toxicity, making them suitable for potential medical and technological applications such as magnetic hyperthermia cancer treatment and catalysis.

NANOMATERIALS (2023)

Article Horticulture

Breakthrough Analysis of Chemical Composition and Applied Chemometrics of European Plum Cultivars Grown in Norway

Milica Fotiric Aksic, Zivoslav Tesic, Milica Kalaba, Ivanka Ciric, Lato Pezo, Biljana Loncar, Uros Gasic, Biljana Dojcinovic, Tomislav Tosti, Mekjell Meland

Summary: The aim of this study was to identify the chemical parameters for distinguishing plum cultivars grown in different regions of Norway. Chemical analysis of 68 plum cultivars revealed variations in the contents of elements, sugars, organic acids, phenolic compounds, and antioxidant activity. These differences have implications for human health and future breeding efforts.

HORTICULTURAE (2023)

暂无数据