期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 17, 期 5, 页码 578-585出版社
SPRINGERNATURE
DOI: 10.1039/c7pp00400a
关键词
-
资金
- Agence Nationale de la Recherche (ANR)
Six new carbazole based compounds (Ca1-Ca6) are synthesized and proposed as high performance photoinitiators with iodonium salt (iod) and/or an amine (EDB) for both the free radical polymerization (FRP) of acrylates and the cationic polymerization (CP) of epoxides upon near UV and visible light exposure using light emitting diodes (LEDs) @385 nm and @405 nm. Excellent polymerization initiating abilities are found and high final reactive function conversions are acquired. A full picture of the involved photochemical mechanisms is given.
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