期刊
ORGANOMETALLICS
卷 37, 期 4, 页码 584-591出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00902
关键词
-
资金
- National Natural Science Foundation of China [21672209]
Ruthenium(II) hydride complexes bearing a pyrazolyl-(2-indol-1-yl)-pyridine ligand were synthesized and structurally characterized by NMR analysis and X-ray single crystal crystallographic determinations. These complexes efficiently catalyzed acceptorless dehydrogenation of N-heterocycles and secondary alcohols, respectively, exhibiting highly catalytic activity with a broad substrate scope. The present work has established a strategy to construct highly active transition metal complex catalysts and provides an atom-economical and environmentally benign protocol for the synthesis of aromatic N-heterocydic compounds and ketones.
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