期刊
ORGANIC LETTERS
卷 20, 期 7, 页码 1866-1870出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00393
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资金
- Alexander von Humboldt Foundation
A palladium-catalyzed intermolecular direct C-H allylation of polyfluoroarenes with alkynes is reported. Unlike classic hydroarylation reactions, alkynes are used as allylic electrophile surrogates in this direct aromatic C-H allylation. As an atom-economic and efficient method, various linear allylated fluoroarenes were synthesized from two simple and easy-to-access feedstocks in good to excellent yields, as well as regio- and stereoselectivity.
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