期刊
ORGANIC LETTERS
卷 20, 期 12, 页码 3579-3582出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01366
关键词
-
资金
- JSPS KAKENHI Grant [JP23000006, JP16H06351, JP16H04107, JP18H04391]
The total syntheses of pusilatins A (2), B (3), and C (5), macrocydic bisbibenzyl dimers isolated from Japanese liverwort are reported. The common monomeric unit (6) was prepared via macrocyclization of an o-sulfinyffluorobenzene derivative by SNAr attack of an internal phenol, which was exploited for site-selective dimerizations en route to 2, 3, and 5.
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