期刊
ORGANIC LETTERS
卷 20, 期 12, 页码 3443-3446出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00981
关键词
-
资金
- Natural Science Foundation of China [21702113, 21602119, U1504208]
- China Postdoctoral Science Foundation
Electrochemical generation of N-acyloxy amidyl radicals via an inner-sphere electron-transfer process is described for the first time. With NaBr as the catalyst and electrolyte, the in situ generated amidyl radicals undergo intramolecular C(sp(2)/sp(3))-H aminations to give lactams with unprecedented regio- and chemoselectivities. Moreover, the synthetic utility of current method is demonstrated by the synthesis of PJ34 and Phenaglaydon.
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