期刊
ORGANIC LETTERS
卷 20, 期 11, 页码 3323-3326出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01214
关键词
-
资金
- Ecole Polytechnique Federale de Lausanne (EPFL)
A simple and versatile method for the preparation of linear, trisubstituted triazenes is reported. The procedure is based on the reaction of Grignard reagents with 1-azido-4-iodobutane or 4-azidobutyl-4-methylbenzenesulfonate. These organic azides enable the regioselective formation of triazenes via an intramolecular cyclization step. The new method can be used for the preparation of aryl, heteroaryl, vinyl, and alkyl triazenes. The synthetic utility of vinyl triazenes is demonstrated by acid induced C-N, C-O, C-F, C-P, and C-S bond-forming reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据