期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 15, 页码 2629-2633出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00635k
关键词
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资金
- National Natural Science Foundation of China [21502177]
- Scientific and Technological Breakthrough Plan of Henan Province [182102310903]
- Science and Technology Research Key Project of the Department of Education of Henan Province [15A150005]
- Doctoral Research Foundation of Zhengzhou University of Light Industry [2014BSJJ032]
- Grants Program of Youth Backbone Teachers Training Object of Zhengzhou University of Light Industry
An iodine-mediated formal oxidative cycloaddition of amidines with tertiary amines was first demonstrated in air. Both symmetrical and unsymmetrical 2,4-disubstituted 1,3,5-triazines were obtained in up to 85% yields. It is noted that a tertiary amine was employed as a one carbon synthon of 1,3,5-triazines and two C-N bonds were formed in one pot. Control experiments revealed that the reaction underwent a radical pathway promoted by I+. The method is transition-metal-free, peroxide-free, and operationally simple to implement with a wide scope of substrates.
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