4.6 Article

Near-infrared luminescence of Bi2ZnOB2O6:Nd3+/PMMA composite

期刊

OPTICAL MATERIALS
卷 75, 期 -, 页码 13-18

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.optmat.2017.10.013

关键词

Melilite-type borates; Bi2ZnOB2O6; Rare earth ions; Neodymium; Luminescence; Polymer-based composites

资金

  1. Polish Ministry of Sciences and Higher Education [06/65/DSPB/5172]

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Near-infrared luminescence of a novel polymer composite system: PMMA doped with Bi2ZnOB2O6:Nd3+ microparticles, is reported for the first time. Luminescence properties of Bi2ZnOB2O6:Nd3+/PMMA were analyzed on the basis on excitation and emission spectra as well as fluorescence decay profiles. Excitation spectra monitored at 1062 nm (F-4(3/2) -> I-4(11/2)) indicate numerous bands related to the optical transition of Nd3+ ions: from the I-4(9/2) ground state to the n D-4(3/2), P-2(1/2), K-2(15/2), (4)G(7/2) + (4)G(9/2), K-2(13/2), (4)G(5/2) + (2)G(7/2), H-2(11/2), F-4(9/2), F-4(7/2) + S-4(3/2), F-4(5/2) + H-2(9/2), F-4(3/2) excited states. Many of them may be utilized to excite near-infrared emission of Ni3+ ions. In particular, distinctive Nd3+ emissions of the F-4(3/2) -> I-4(9/2) and F-4(3/2) -> I-4(11/2) transitions were detected, under excitation at 514 nm. The fluorescence decay profiles monitored at 1062 nm, excited at 514 nm, show relatively long emission lifetime of the F-4(3/2) -> I-4(11/2) transition equal to 85 mu s. Raman spectroscopy was used to determine vibrational properties and homogeneity of Bi2ZnOB2O6:Nd3+/PMMA composites. The obtained results suggest that Bi2ZnOB2O6:Nd3+/PMMA composite may be applied as an effective source of near-infrared emission in a new integrated optoelectronic devices. (C) 2017 Elsevier B.V. All rights reserved.

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