Article
Chemistry, Multidisciplinary
Rui P. C. L. Sousa, Rita B. Figueira, Barbara R. Gomes, Sara Sousa, R. Cristina M. Ferreira, Susana P. G. Costa, M. Manuela M. Raposo
Summary: This study reports the preparation of organic-inorganic hybrid materials (OIH) doped with different imidazole compounds using the sol-gel method, combining the advantages of organic and inorganic components. The optical properties of the materials were altered by the presence of the imidazole compounds, demonstrating a synergetic effect between the matrix's intrinsic emission and the fluorescence of the imidazole compounds.
Article
Chemistry, Analytical
Guiqiao Wang, Shurong Zhang, Jinzhi Cui, Wensu Gao, Xing Rong, Yaxin Lu, Canzhu Gao
Summary: A novel ionic sensor based on nitrogen-doped carbon quantum dots (N-CQDs) was developed for sensitive detection of hypochlorite ions and dichromate ions by fluorescence spectrometry. The sensor exhibited high fluorescence quantum yield, broad linear detection range, and good reliability in actual water sample analysis.
ANALYTICA CHIMICA ACTA
(2022)
Article
Materials Science, Multidisciplinary
Xuan Zhang, Huazhang Guo, Changhan Chen, Biao Quan, Zhiming Zeng, Jing Xu, Zeyu Chen, Liang Wang
Summary: Photoacoustic-fluorescence imaging is a promising medical imaging technology that offers real-time, fast, and highly sensitive imaging capabilities for specialties such as ophthalmology, otorhinolaryngology, and dermatology. A series of nitrogen-doped carbon quantum dots (N-CQDs) with narrow size distribution and tunable optical capability were synthesized through a molecular fusion strategy. The N-CQDs demonstrated fast imaging velocity, rapid metabolism, and enhanced permeability and retention effect, enabling better accumulation in the tumor region. The molecular fusion strategy provides a guideline to design advanced N-CQDs for comprehensive and accurate tumor imaging.
APPLIED MATERIALS TODAY
(2023)
Article
Chemistry, Analytical
Xiufen Liao, Congjin Chen, Jielun Yang, Ruxia Zhou, Lulu Si, Quanlong Huang, Zuqiang Huang, Chunqiu Lv
Summary: N-doped carbon dots (N-CDs) were synthesized by hydrothermal treatment of cellobiose and urea, and a novel anti-false-positive mechanism for phosalone identification was achieved. The constructed sensor showed comparable accuracy and precision to the standard gas chromatographic (GC) method, with excellent recovery rates and low relative standard deviations (RSD).
Article
Chemistry, Multidisciplinary
Yaoyao Feng, Yujiao Qu, Xiaobo Sun, Wei Pan, Jinping Wang
Summary: A dual-mode detection method using carbon dots and 5,5-dithiobis-(2-nitrobenzoic acid) was developed for the detection of organophosphorus pesticides. This method demonstrated high selectivity, sensitivity, and accuracy, with a low detection limit.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Demin Huang, Haiyan Qi, Jing Jing, Rokayya Sami, Tao Jing, Sultan J. Alsufyani, Nada Benajiba, Nawal Madkhali
Summary: Nitrogen-doped carbon dots (F-NCDs) were prepared through a one-step hydrothermal method, and the emission wavelength could be tuned by introducing new energy levels. The F-NCDs exhibited stability under illumination, ionic strength, and pH conditions, and showed specificity and sensitivity in ascorbic acid detection. With full-color emission features, the F-NCDs have great potential in fluorescent sensor detection.
Article
Spectroscopy
Liuxi Zhao, Xiyue Cao, Xuanfeng Jang, Yuhong Zhang, Bin Shang, Zhengguang Sun, Yuan Zhan
Summary: In this study, nitrogen-doped carbonized polymer dots (HNCDs) with self-quenching-resistant fluorescence were prepared by a simple solvothermal method. The HNCDs showed excellent stability, optical properties, and low cost, making them highly promising for optoelectronic devices. The modification of poly(HEMA) on the surface of carbonized core effectively overcame the quenching effect, while nitrogen doping played a crucial role in the red shift emission of solid-state HNCDs. Furthermore, the concentration-dependent emission and compatibility with silicone sol enabled the preparation of multicolor LEDs ranging from blue to red.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Spectroscopy
Kunfeng Liu, Chongshu Xia, Yahui Guo, Hang Yu, Yunfei Xie, Weirong Yao
Summary: Surface modification of N, S-CDs was performed using cysteine and polyethylenimine as raw materials. The prepared N, S-CDs exhibited excitation-independent in the range of 300-380 nm. A fluorescence sensor with high sensitivity and selectivity to detect Hg2+ was developed based on the quenching effect of Hg2+ on the fluorescence intensity of N, S-CDs.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Spectroscopy
Subrata Mondal, Priti Gupta, Fazlur Rahaman, Prabhat Gautam, I. C. Lekshmi
Summary: Thiazole based receptor was designed and synthesized for colorimetric and fluorimetric detection of fluoride ion. The receptor showed significant absorption and fluorescence changes in the presence of fluoride ions, with high detection sensitivity.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Spectroscopy
Hongxia Qi, Zizhuo Zhai, Xipeng Dong, Pudun Zhang
Summary: A highly luminescent nitrogen-doped carbon quantum dots were prepared and used to develop a sensitive and selective quantification method for detecting hypochlorite ions. The method showed excellent linearity, low detection and quantification limits, and was successfully applied in real water samples and text encryption.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Analytical
Qiang Bai, Hongyang Luo, Xuetao Yi, Shugao Shi, Lina Wang, Manhong Liu, Fanglin Du, Zhugen Yang, Ning Sui
Summary: Nitrogen-doped graphdiyne dots (N-GDQDs) were synthesized for the first time by a simple hydrothermal method. The N-GDQDs showed good electronic, optical, and electrochemical properties. They were used to construct an optical electrochemical nanosensor for sensitive and selective detection of dopamine (DA).
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Wei Wei, Juan Huang, Wenli Gao, Xiangyang Lu, Xingbo Shi
Summary: Blue emission carbon dots (CDs) were synthesized using naringin as precursor in this study, and were utilized to develop a ratiometric fluorescence sensor for sensitive analysis of Al3+ with high accuracy. The color change of CDs probe from blue to green under UV lamp, combined with smartphone and RGB analysis, allows for visual detection of Al3+ with high sensitivity.
Article
Chemistry, Multidisciplinary
Jianbo Huang, Xin Liu, Lijun Li, Sheng Chen, Jun Yang, Jipeng Yan, Feng Xu, Xueming Zhang
Summary: Carbon quantum dots (CQDs) are novel fluorescent materials with potential applications in sensing and bioimaging. A smart switch sensor hydrogel (SWSH) was successfully prepared by incorporating nitrogen-doped carbon quantum dots (N-CQDs) into a polyacrylamide (PAM) hydrogel network, enabling the recognition of metal ions and reversible fluorescence response. The N-CQDs in the SWSH formed complexes with Cu2+ or Ag+ ions, allowing for on/off fluorescence response and recognition of metal ions through observable fluorescence changes.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Materials Science, Multidisciplinary
Jinyan Du, Na Xu, Chaofeng Wang, Qin Shu, Qidi Xu, Ping Zhang, Shujuan Zhuo, Changqing Zhu
Summary: Novel B, N, S-co-doped carbon dots were synthesized and found to exhibit pH-responsive fluorescence and Ag+ ion detection capability, making them promising dual probes for biosensing.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Chemistry, Analytical
Yen-Linh Thi Ngo, Phi Luan Nguyen, Jayasmita Jana, Won Mook Choi, Jin Suk Chung, Seung Hyun Hur
Summary: A new strategy for sensing hydrogen peroxide (H2O2) and glucose using metal oxide-carbon dot hybrid structure was investigated. The sensing system showed high accuracy in detecting H2O2 and glucose and could be applied for on-site analysis of glucose without the use of a spectrometer.
ANALYTICA CHIMICA ACTA
(2021)
Article
Nanoscience & Nanotechnology
Xi Chen, Wenwen Zhang, Lixiang Zhang, Luping Feng, Chunxian Zhang, Jie Jiang, Hua Wang
Summary: A selective photoelectrochemical sensor has been developed using g-C3N4 nanosheets treated with N-2 plasma to deposit Cd probes for signal-on detection of H2S. The Cd/N@g-C3N4 nanocomposites exhibit enhanced photocurrent responses to H2S under visible light irradiation due to the formation of efficient CdS heterojunctions. This novel sensing platform shows promise for applications in environmental monitoring, food safety, and biomedical analysis.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Xiurong Zhai, Fan Xu, Yujiao Li, Fangying Jun, Shuai Li, Chunxian Zhang, Hua Wang, Bingqiang Cao
Summary: Silver-doped ZnO nanorods arrays grown in-situ onto ITO via one-pot hydrothermal route show highly selective and recyclable electroanalysis of phosphothioate pesticides, with good detection performance and photocatalytic degradation efficiency.
ANALYTICA CHIMICA ACTA
(2021)
Article
Engineering, Environmental
Mengyuan Yin, Yuqi Wan, Shuai Li, Xiaoting Zhao, Wenwen Zhang, Yun Zhang, Hua Wang
Summary: Mesoporous melamine-silver nanocomposites doped with carbon nitride quantum dots were fabricated through controlled supramolecular self-assembly. The resulting nanoflower-like nanocomposites exhibited peroxidase-like catalysis, which could be enhanced by Hg2+ and effectively detoxify Hg-0 in wastewater through visible-light-driven photocatalysis. These nanocomposites also showed high Hg adsorption capability and promise for environmental monitoring and wastewater treatment of toxic heavy metals.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Xi Chen, Wenwen Zhang, Lixiang Zhang, Luping Feng, Chunxian Zhang, Jie Jiang, Hua Wang
Summary: The porous In2S3@In2O3 composites, prepared by special treatment, exhibited efficient photocatalytic production of H2O2 in pure water, showing promising application prospects.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Analytical
Xiurong Zhai, Shuai Li, Yukun Wang, Siyu Cao, Wen Sun, Mingzhu Liu, Guojiang Mao, Bingqiang Cao, Hua Wang
Summary: A magnet-renewable electroanalytical strategy has been developed for monitoring hydrogen sulfide (H2S) in aquaculture freshwater systems using magnetic Fe3O4-loaded silver metal-organic framework (Fe3O4@Ag-MOF). The method exhibits sensitive and stable signals with rational signal decline in the presence of H2S. The electrodes can be easily renewed for immobilization of Fe3O4@Ag-MOF probes, facilitating detection in aquaculture freshwater samples.
ANALYTICA CHIMICA ACTA
(2022)
Article
Nanoscience & Nanotechnology
Huimin Zhou, Yao Jiang, Wenjing Zhao, Shusheng Zhang
Summary: In this study, a light-activated nanodevice based on DNA nanotechnology was constructed for high precision detection of low-abundance miRNA. The nanodevice enabled on-demand imaging of miRNA in living cells with high spatial and temporal control.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Analytical
Chunxian Zhang, Shuai Li, Zhiqiang Duan, Qin Li, Mengxuan Zhao, Yulong Chen, Xiurong Zhai, Guojiang Mao, Hua Wang
Summary: Water-soluble non-conjugated polymer dots were synthesized using hyperbranched polyethyleneimine and dihydroxybenzaldehyde for the first time. These polymer dots exhibited strong green fluorescence in aqueous media and could be quenched by MnO2 nanosheets and restored by thiocholine. A highly selective fluorimetric method for detecting organophosphorus pesticides was developed based on these characteristics.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Yao Jiang, Huimin Zhou, Wenjing Zhao, Shusheng Zhang
Summary: This study presents a self-assembled three-dimensional (3D) DNA nanostructure drug delivery system that utilizes ATP-triggered drug release for tumor fluorescence imaging and targeted therapy. The Dox@3D DNA nanostructures are assembled through a simple annealing reaction and can release drugs rapidly in tumor cells induced by high concentrations of ATP, providing efficient accumulation of drugs in tumors and minimizing damage to normal tissues.
ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Analytical
Luping Feng, Lixiang Zhang, Su Chu, Sheng Zhang, Xi Chen, Yushuang Gong, Zhongling Du, Guojiang Mao, Hua Wang
Summary: A nanozyme with a 2D/1D heterostructure, SWCNTs@MoS2, was successfully fabricated and demonstrated improved peroxidase-like catalysis, along with selective detection of glutathione (GSH). A colorimetric method based on SWCNTs@MoS2 was proposed for quantitative analysis of GSH, showing potential for extensive applications in clinical laboratory settings. This study opens up possibilities for designing various nanozymes with enhanced catalytic activity.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Chenchen Xu, Qingqing Liu, Su Chu, Pan Li, Fengxiang Wang, Yanmei Si, Guojiang Mao, Choufei Wu, Hua Wang
Summary: A microdots array-based fluoremetric method with superwettability profile was developed for simultaneous and separate detection of Fe3+ and Cu2+ ions in red wine samples. The fluoremetric microdots array platform was obtained by designing a wettable micropores array and immobilizing fluorescent probes in it. The platform enabled the accumulation of targeting ions without tedious preprocessing and reduced cross-contamination. The feasibility of simultaneous and separate detection of Fe3+ and Cu2+ ions in red wine samples was demonstrated.
ANALYTICA CHIMICA ACTA
(2023)
Article
Chemistry, Analytical
Yuchun Qiao, Yu Fang, Jizhen Shang, Xiaoting Zhao, Shuai Li, Guojiang Mao, Hua Wang
Summary: In this study, a fluorescent test strip with suppressed CRE of silver nanocluster probes coated by gelatin was successfully fabricated using vacuum-aided fast lyophilization, enabling uniform and stable probe deposition as well as sensitive quantitative analysis.
Article
Chemistry, Analytical
Wenjing Zhao, Yao Jiang, Huimin Zhou, Shusheng Zhang
Summary: DNA self-assembling nanoprobes with self-transferability and resistance to nuclease degradation have been developed and applied in live cell bio-imaging. A hairpin-functionalized DNA tetrahedron (HFDT) intramolecular catalytic self-assembly platform was designed to detect low-abundance miRNAs using catalyzed hairpin assembly (CHA). This innovative strategy effectively changes the distribution and properties of biomaterials, increases accumulation of nanomaterials at the tumor site, and has promising applications in tumor imaging.
Article
Materials Science, Biomaterials
Sheng Zhang, Luping Feng, Pan Li, Lixiang Zhang, Xi Chen, Su Chu, Yuan Gao, Shujing Xie, Jiatian Jiang, Hua Wang
Summary: A highly selective and sensitive photoelectrochemical detection method using ZnO@CdS heterojunctions was developed for the analysis of copper ions. The rational combination of photosensitive catalyst and visible-light sensitizer enhanced the detection of Cu2+ ions with linear concentrations in blood.
JOURNAL OF MATERIALS CHEMISTRY B
(2021)
Article
Materials Science, Biomaterials
Pan Li, Lixiang Zhang, Sheng Zhang, Chenchen Xu, Yinuo Li, Juan Qu, Shuai Li, Guojiang Mao, Hua Wang
Summary: A high-throughput and selective fluorimetric platform has been developed for analyzing ammonia in blood using a polymer-stabilized metal-organic framework and wettable microwells array construction. Plasma treatment of ITO substrate created a super-hydrophilic interface for wettable microwells array construction, enabling enrichment of targets from sample droplets.
JOURNAL OF MATERIALS CHEMISTRY B
(2021)
Article
Chemistry, Multidisciplinary
Kelu Yan, Min Liu, Jiangwei Wen, Xiao Liu, Xinyue Wang, Xinyu Chen, Jing Li, Shao Wang, Xiu Wang, Hua Wang
Summary: The visible-light-promoted cascade cyclization of 2-haloaryl isothiocyanates and isocyanides to access benzo[d]imidazo[5,1-b]thiazoles has been efficiently realized under metal- and photocatalyst-free conditions. This protocol offers advantages such as readily available and inexpensive substrates, metal catalyst-free, step and atom economy, and mild reaction conditions.
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)