期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 11, 页码 8342-8345出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj00892b
关键词
-
资金
- National Natural Science Foundation of China [21671066, 21171056]
We have developed the regiospecific and stereoselective synthesis of (E)- and (Z)-2-phosphino-1-alkenyl boronates via Cu-catalyzed hydroboration of alkynylphosphines. A remarkable ligand-controlled stereoselectivity in the transformation is presented. The study on the coordination chemistry of the new phosphine/borane compounds with gold suggests the presence of very weak Au B interaction in the gold complex 4 ligated by (E)-2-phosphino-1-alkenyl boronate 2a.
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