4.6 Article

Electrodepositing ultra-thin Ni(OH)(2) amorphous film on Ni2P nanosheets array: an efficient strategy toward greatly enhanced alkaline hydrogen evolution reaction

期刊

NEW JOURNAL OF CHEMISTRY
卷 42, 期 14, 页码 11285-11288

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj01910j

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资金

  1. National Natural Science Foundation of China [21775063, 21575056, 21645001]
  2. Shandong Provincial Natural Science Foundation [ZR2017BB065, ZR2016JL010, ZR2017PC005, ZR2016QZ001, ZR2014BL025, ZR2016BL20]
  3. Primary Research and Development Plan of Shandong Province [2018GSF118172]

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The development of highly active noble-metal-free catalysts for alkaline hydrogen evolution reaction (HER) can greatly lower the cost of hydrogen economy and boost the utilization of clean and renewable energy. Herein, we report an interface-engineered nanostructure (Ni(OH)(2)-Ni2P/Ti) as a highly efficient HER catalyst. Impressively, the newly generated hybrid catalyst exhibits superior catalytic activity when compared to that of pristine Ni2P/Ti. It only requires overpotentials of 57 and 85 mV to afford current densities of 10 and 20 mA cm(-2) in 1.0 M KOH, respectively, with its catalytic activity being retained for 24 h.

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