4.3 Article

A Facile Method for Loading CeO2 Nanoparticles on Anodic TiO2 Nanotube Arrays

期刊

NANOSCALE RESEARCH LETTERS
卷 13, 期 -, 页码 -

出版社

SPRINGER
DOI: 10.1186/s11671-018-2504-7

关键词

Anodic TiO2 nanotubes; CeO2 nanoparticles; CeO2/TiO2 heterojunctions; Green chemistry

资金

  1. National R&D Program of China [2017YFA0207400]
  2. National Key Research and Development Plan [2016YFA0300801]
  3. National Natural Science Foundation of China [51502033, 61571079, 61131005, 51572042]
  4. National Basic Research Program of China [2012CB933104]
  5. 111 Project [B13042]
  6. International Cooperation Projects [2015DFR50870]
  7. Science and Technology project of Sichuan Province [2017JY0002]

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In this paper, a facile method was proposed to load CeO2 nanoparticles (NPs) on anodic TiO2 nanotube (NT) arrays, which leads to a formation of CeO2/TiO2 heterojunctions. Highly ordered anatase phase TiO2 NT arrays were fabricated by using anodic oxidation method, then these individual TiO2 NTs were used as tiny nano-containers to load a small amount of Ce(NO3)(3) solutions. The loaded anodic TiO2 NTs were baked and heated to a high temperature of 450 degrees C, under which the Ce(NO3)(3) would be thermally decomposed inside those nano-containers. After the thermal decomposition of Ce(NO3)(3), cubic crystal CeO2 NPs were obtained and successfully loaded into the anodic TiO2 NT arrays. The prepared CeO2/TiO2 heterojunction structures were characterized by a variety of analytical technologies, including XRD, SEM, and Raman spectra. This study provides a facile approach to prepare CeO2/TiO2 films, which could be very useful for environmental and energy-related areas.

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