期刊
NANO RESEARCH
卷 11, 期 3, 页码 1301-1312出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-017-1744-7
关键词
Kirkendall diffusion; nanoplate; tin oxide; lithium-ion battery; spray pyrolysis
类别
资金
- National Research Foundation of Korea (NRF) grant - the Korea government (MEST) [2017R1A2B2008592]
Herein, hierarchically structured SnO2 microspheres are designed and synthesized as an efficient anode material for lithium-ion batteries using hollow SnO2 nanoplates. Three-dimensionally ordered macroporous (3-DOM) SnOx-C microspheres synthesized by spray pyrolysis are transformed into hierarchically structured SnO2 microspheres by a two-step post-treatment process. Sulfidation produces hierarchically structured SnS-SnS2-C microspheres comprising tin sulfide nanoplate and carbon building blocks. A subsequent oxidation process produces SnO2 microspheres from hollow SnO2 nanoplate building blocks, which are formed by Kirkendall diffusion. The discharge capacity of the hierarchically structured SnO2 microspheres at a current density of 5 A.g(-1) for the 600th cycle is 404 mA.h.g(-1). The hierarchically structured SnO2 microspheres have reversible discharge capacities of 609 and 158 mA.h.g(-1) at current densities of 0.5 and 30 A.g(-1), respectively. The ultrafine nanosheets contain empty voids that allow excellent lithium-ion storage performance, even at high current densities.
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