期刊
MINI-REVIEWS IN ORGANIC CHEMISTRY
卷 15, 期 4, 页码 283-290出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570193X15666180101150819
关键词
Carbon dioxide; carboxylation; terminal alkyne; propiolic acids; transition metal; catalysis
资金
- National Key Research and Development Program [2016YEA0602900]
- National Natural Science Foundation of China [21472103, 21421001, 21421062, 21672119]
- Natural Science Foundation of Tianjin Municipality [16JCZDJC39900]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130031110013]
- MOE Innovation Team of China [IRT13022]
The coupling reaction of terminal alkynes and CO2 provides a promising way to synthesize propiolic acids. Among the existing catalytic systems, transition-metal copper and silver exhibit excellent catalytic efficiency under mild conditions probably being attributed to the activation of C-C triple bond of terminal alkynes. In this aspect, efficient strategies for activating both substrate and CO2 are often smart choices. This review summarizes the development trend of the Cu/Ag-catalyzed carboxylation reactions of terminal alkynes with CO2, and representative examples are also discussed in detail.
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