Article
Nanoscience & Nanotechnology
Zhen Xu, Zhiwei Lv, Chuan Guo, Yang Zhou, Gan Li, Xiaogang Hu, Xinggang Li, Qiang Zhu
Summary: The steady-state creep mechanisms of a superlattice gamma'-strengthened Co-Al-W-Ta-Ti single crystal superalloy were studied under different temperature and stress conditions. The microstructures of the creep samples varied significantly according to the experimental conditions. Lomer-Cottrell locks and stacking faults interactions dominated the low-temperature and high-stress creep regime, while dislocations cross-slip and dislocation tangles contributed to the main creep resistance at intermediate temperatures and moderate stresses. The interactions of stacking faults and dislocation networks were the strengthening mechanism for the high-temperature and low-stress creep regime. The steady-state creep rate followed a classical power law equation, with a calculated creep activation energy of 378.46 kJ/mol. These findings provide insights into the effects of temperature and stress on steady-state creep mechanisms, and highlight the potential of the gamma'-strengthened Co-Al-W-Ta-Ti single crystal superalloy as a high-temperature structural material.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Materials Science, Multidisciplinary
N. Volz, F. Xue, C. H. Zenk, A. Bezold, S. Gabel, A. P. A. Subramanyam, R. Drautz, T. Hammerschmidt, S. K. Makineni, B. Gault, M. Goeken, S. Neumeier
Summary: The study found that at high temperatures, solutes such as Al, W, and Ta diffuse faster, leading to segregation and accelerated softening of the alloy, affecting creep properties. Partial dislocations facilitate shearing of the γ' precipitate phase through segregation during the early stages of creep. Thus, the poorer creep properties of the alloy at high temperatures are not only due to a smaller precipitate fraction, but also to faster diffusion-assisted shearing by partial dislocations.
Article
Materials Science, Multidisciplinary
Shujing Shi, Zhengwei Yan, Yongsheng Li, Dong Wang, Zhiheng An, Gang Sha, Yang Wang, Yan Zhao
Summary: The study investigated the effects of aging temperature on the precipitation of the gamma '-Co-3(Al, W) phase in a Co-9Al-8W alloy. The results showed rapid increase in alloy microhardness at 1073 K, indicating precipitation strengthening. Partitioning coefficients of Al and W in the gamma ' phase were more obvious at 1073 K. The particle size distribution of the gamma ' phase matched different models at different growth stages.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Manufacturing
Boryung Yoo, Chanwon Jung, KenHee Ryou, Won Seok Choi, Lukas Haussmann, Sangsun Yang, Torben Boll, Steffen Neumeier, Pyuck-Pa Choi
Summary: In this study, Co-Al-W superalloys were fabricated by laser-directed energy deposition and investigated for their susceptibility to hot-cracking. It was found that the alloy with higher aluminum content exhibited better resistance to cracking due to the formation of a protective oxide layer. Heat treatment resulted in a homogeneous microstructure and improved printability of the alloy.
ADDITIVE MANUFACTURING
(2022)
Article
Nanoscience & Nanotechnology
Pengfei Qu, Wenchao Yang, Chen Liu, Jiarun Qin, Haijun Su, Jun Zhang, Lin Liu
Summary: In this study, the creep properties of a Ni-based single crystal superalloy in [011] orientation at intermediate temperatures were investigated. The damage mechanism resulting from orientation rotation was proposed. It was found that the deformation microstructure depended on the distance from the fracture, with micro-twins observed at farther positions and stacking faults at nearer positions. Both micro-twins and stacking faults originated from the activity of a single {111} <112> slip system. The asynchrony of orientation rotation caused nonuniform deformation and localized force inhomogeneity, leading to premature failure of the specimen.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Chemistry, Physical
J. M. Bai, H. P. Zhang, X. Y. Li, J. T. Liu, Q. S. Sun, C. S. Liu, Y. W. Zhang
Summary: This study conducted creep rupture tests on powder metallurgy superalloys with various Ta additives to further understand the effect of Ta on creep damage. The results showed that multiple crack propagation and damage mechanisms could occur under the same creep condition, and the addition of Ta could alter the size of these different fracture mode areas. However, the effects of Ta changed significantly under different creep conditions.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
L. Heep, D. Burger, C. Bonnekoh, P. Wollgramm, A. Dlouhy, G. Eggeler
Summary: The low temperature high stress tensile creep behavior of the superalloy single crystal ERBO-1 was investigated, with comparisons made between loading directions of [001] and deviations towards [111] and [011]. The study found that creep rates are influenced by the loading directions, and faster creep rates are observed when dislocations from two octahedral systems experience similar driving forces.
SCRIPTA MATERIALIA
(2022)
Article
Materials Science, Multidisciplinary
Vassili A. Vorontsov, Thomas P. McAuliffe, Mark C. Hardy, David Dye, Ioannis Bantounas
Summary: The tensile creep performance of a polycrystalline Co/Ni-base superalloy with a multimodal gamma' distribution was studied at 800 degrees C and 300 MPa. The rupture life of the alloy was comparable to that of RR1000 tested under similar conditions. Microstructural examination revealed the presence of continuous gamma' precipitates and M23C6 carbides along the grain boundaries, as well as the coarsening of the secondary gamma' precipitates. Long planar deformation bands, identified as microtwins, were observed along with the depletion of gamma' stabilising elements. The mechanism for precipitate dissolution was suggested to be the Kolbe reordering mechanism.
Article
Materials Science, Multidisciplinary
F. D. Leon-Cazares, R. Schlutter, F. Monni, M. C. Hardy, C. M. F. Rae
Summary: This study provides experimental evidence, using transmission electron microscopy, for the nucleation mechanism of superlattice intrinsic stacking faults (SISF) in polycrystalline alloys. The concept of a nascent fault is introduced, and the stress and dislocation types involved in the subsequent dislocation evolution are detailed.
Article
Nanoscience & Nanotechnology
Junyang He, Lijie Cao, Surendra Kumar Makineni, Baptiste Gault, Gunther Eggeler
Summary: During high temperature and low stress creep, nanometer-scale mass flow coupled to dislocation processes near the gamma/gamma'-interface was investigated in a model Ni-base single crystal superalloy. In the early creep stages, compositional gradients close to the interface were observed as dislocation networks attracted gamma-stabilizing elements. However, at larger strains where dislocations cut into the gamma'-phase, the local interfacial enrichment in these elements was no longer observed. The cutting dislocations took segregated atoms away, while the remaining atoms were released and diffused back into the gamma-channels.
SCRIPTA MATERIALIA
(2021)
Article
Nanoscience & Nanotechnology
Yu Li, Zhenjun Hong, Binggang Liu, Xiaoshuai Jia
Summary: The microstructure evolution and mechanical properties were investigated in a multi-precipitation Ni-Co base superalloy system with different chemical compositions. The interaction of multi-precipitates and its influence on the creep behavior were studied, showing that the 2# Ni-Co alloy exhibits significantly higher creep strain rate and an advanced accelerating creep stage compared to the 1# Ni-Co alloy during creep process.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Nanoscience & Nanotechnology
Jinbin Chen, Qianyu Huo, Jingyang Chen, Yidong Wu, Qing Li, Chengbo Xiao, Xidong Hui
Summary: By combining thermodynamic calculations and orthogonal experiment approach, the composition optimization of Mo, W and Ti elements in second-generation Ni-based single crystal superalloys was conducted to develop alloys with superior creep resistance performance. The influence of alloying elements on phase composition was discussed, and quantitative relations between creep lives and solid solution strengthening index, volume fraction of gamma' precipitates and TCP phases were established. Eventually, an appropriate composition range of Mo, W and Ti elements was confined, leading to the development of Ni-based single crystal superalloys with superb creep resistance performance.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Yu Shi, Cuiping Guo, Changrong Li, Zhenmin Du, Die Hu
Summary: The microstructures of annealed alloys and XRD patterns of partial critical alloys in the Co-Ti-W system were investigated. The isothermal sections at different temperatures were established, and it was found that the addition of W element can improve the stability of the L1(2) crystal structure in the Co-Ti-W system.
FRONTIERS IN MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
N. Volz, F. Xue, A. Bezold, C. H. Zenk, S. G. Fries, J. Schreuer, S. Neumeier, M. Goeken
Summary: The study designed a series of Ta-containing Co-based alloys with systematically varying gamma ' volume fractions, and found phase transformations related to alloy composition and heat treatment conditions.
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
(2021)
Review
Materials Science, Multidisciplinary
Yunsong Zhao, Yuheng Zhang, Yi Zhang, Yushi Luo, Dingzhong Tang, Haitao Liu, Huadong Fu
Summary: Co-Al-W-based superalloys show excellent deformation and creep properties, making them suitable for high-temperature structural materials. Further research is needed to clarify the relationship between microstructure and properties for guidance on composition design and heat treatment optimization.
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
(2021)