4.6 Article

Facile preparation of zinc oxide nanorods surrounded by graphene quantum dots both synthesized via separate pyrolysis procedures for photocatalyst application

期刊

MATERIALS RESEARCH BULLETIN
卷 98, 期 -, 页码 148-154

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2017.10.014

关键词

Zinc oxide; Nanorod; Graphene quantum dot; Photocatalyst; Pyrolysis

资金

  1. Research Council of Tarbiat Modares University

向作者/读者索取更多资源

A facile pyrolysis method was employed for separate synthesis of zinc oxide nanorods (ZnO NRs) and graphene quantum dots (GQDs) and the structures were composited. The structures were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), and Fourier transform infrared (FTIR) spectroscopy. The structures were optically characterized by UV-vis and photoluminescence (PL) spectrometry techniques, showing that the absorption of ZnO NRs increases in the visible region after being surrounded by GQDs. Optical bandgaps of ZnO NRs and ZnO NRs/GQDs composite were estimated as 3.2 and 2.8 eV, respectively. Based on PL analysis, it was deduced that the generated electron hole recombination rate of ZnO NRs decreases after being surrounded by GQDs. Finally, it was shown that our GQDs, despite being relatively inefficient separately, significantly enhance the photocatalytic activity of ZnO on methylene blue mainly through decreasing the e-h recombination rate of ZnO NRs.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Incremental photocatalytic reduction of graphene oxide on vertical ZnO nanorods for ultraviolet sensing

Kourosh Rahimi, Ahmad Yazdani

MATERIALS LETTERS (2020)

Article Engineering, Electrical & Electronic

Effect of Co2+ content on supercapacitance properties of hydrothermally synthesized Ni1-xCoxFe2O4 nanoparticles

Samira Sharifi, Ahmad Yazdani, Kourosh Rahimi

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2020)

Article Materials Science, Multidisciplinary

Possible bandgap values of graphene-like ZnO in density functional theory corrected by the Hubbard U term and HSE hybrid functional

Asiye Shokri, Ahmad Yazdani, Kourosh Rahimi

MATERIALS TODAY COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Incremental substitution of Ni with Mn in NiFe2O4 to largely enhance its supercapacitance properties

Samira Sharifi, Ahmad Yazdani, Kourosh Rahimi

SCIENTIFIC REPORTS (2020)

Article Materials Science, Multidisciplinary

Electric-field- and strain-induced adjustability of vdW heterostructure of g-ZnO/2H-TiS2 for optoelectronic applications

Kourosh Rahimi

Summary: The research proposed a vdW g-ZnO/2H-TiS2 heterostructure adjustable by electric field and strain, featuring a narrow indirect bandgap and large potential drop for optoelectronic devices. Additionally, the study also revealed the tunability of the bandgap and absorption of the heterostructure under different electric fields and strains.

MATERIALS LETTERS (2021)

Article Nanoscience & Nanotechnology

Magnetic anisotropy in Co/phosphorene heterostructure

S. Hamidreza Hoseyni, Kourosh Rahimi, Behrad Barakati, Ali Sadeghi, S. Majid Mohseni

Summary: Magnetic anisotropy (MA) is crucial in the design of future spintronic and magnetic devices, especially in structures with few angstroms thickness. Using first-principles calculations, we found that the interface MA in Co/phosphorene heterostructures is comparable to that of ferromagnet/heavy-metal interfaces, despite the weak spin-orbit coupling strength of phosphorus atoms. Furthermore, the magnetic anisotropy energy (MAE) of the system can be significantly increased by applying strain, with the MA varying from perpendicular to in-plane directions.

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES (2021)

Article Multidisciplinary Sciences

Highly improved supercapacitance properties of MnFe2O4 nanoparticles by MoS2 nanosheets

Samira Sharifi, Kourosh Rahimi, Ahmad Yazdani

Summary: Manganese ferrite (MnFe2O4) nanoparticles were synthesized and combined with exfoliated MoS2 nanosheets to create a nanocomposite for supercapacitors. The addition of MoS2 significantly increased the specific capacitance of MnFe2O4, leading to higher energy density, power density, and improved stability, making it suitable for supercapacitors.

SCIENTIFIC REPORTS (2021)

Article Materials Science, Multidisciplinary

Charge-doping-induced variation of the superconducting BaFe2As2 electronic structure and the emerging physical effects: a DFT plus DMFT study

Mehdi Hesani, Kourosh Rahimi, Ahmad Yazdani

Summary: The study investigated the relationship between charge doping and correlations in BaFe2As2 using DFT+DMFT, showing that electronic correlations strengthen systematically from electron-doping to hole-doping regimes. Due to its multi-orbital nature, correlations in BaFe2As2 are orbital-dependent, with the Fe-3d(xy) orbital exhibiting the most correlation.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Physics, Condensed Matter

Electronic and optical properties of antimonene/palladium ditelluride (Sb/ PdTe2) heterostructure with the effect of strain and external electric field: A computational study

Asiye Shokri, Ahmad Yazdani, Kourosh Rahimi

Summary: The study reveals that the antimonene/palladium ditelluride heterostructure exhibits semiconductor properties and can be controlled to form different types of semiconductors or conductors by changing external electric field and strain parameters. Additionally, the heterostructure shows absorption of light in the ultraviolet and visible regions, indicating its potential for electronic and optoelectronic applications.

PHYSICA B-CONDENSED MATTER (2021)

Article Chemistry, Inorganic & Nuclear

Magnetically Recyclable Fe3O4@TMU-32 Metal-Organic Framework Photocatalyst for Tetracycline Degradation Under Visible Light

Nasrin Abdollahi, Azar Ostovan, Kourosh Rahimi, Mansour Zahedi, Alireza Z. Moshfegh

Summary: Metal-organic frameworks (MOFs) have shown promising potential as photocatalysts for environmental remediation. In this study, TMU-32 MOF exhibited high photocatalytic activity due to its large specific surface area and appropriate band gap energy. Fe3O4@TMU-32 nanocomposite, prepared by combining TMU-32 with Fe3O4 nanoparticles, showed good recyclability and photocatalytic efficiency. This research provides valuable insights for the development of efficient photocatalysts.

INORGANIC CHEMISTRY (2021)

Article Energy & Fuels

Boron- and nitrogen-doped graphene quantum dots with enhanced supercapacitance

Mohamad Taghi Dejpasand, Samira Sharifi, Esmaiel Saievar-Iranizad, Ahmad Yazdani, Kourosh Rahimi

Summary: This study investigated the effect of boron and nitrogen doping on the electrochemical energy storage properties of graphene quantum dots (GQDs), finding that N-GQDs showed higher specific capacitance, specific energy, and specific power compared to GQDs and B-GQDs. Additionally, N-GQDs exhibited better cycling stability with 80% capacity retention.

JOURNAL OF ENERGY STORAGE (2021)

Article Chemistry, Physical

Band alignment tuning of heptazine-g-C3N4/g-ZnO vdW heterostructure as a promising water-splitting photocatalyst

Kourosh Rahimi, Alireza Z. Moshfegh

Summary: The vdW heterostructure of hg-C3N4/g-ZnO has the potential to be a solar-driven photocatalyst for water-splitting reaction with reduced electron-hole recombination rate. By applying external perpendicular electric fields and biaxial strains, band alignment, bandgap energy, and transition type can be tuned to optimize efficiency for water-splitting photocatalysis.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2021)

Article Materials Science, Multidisciplinary

Tunable electronic and optical properties of g-ZnO/α-PtO2 van der Waals heterostructure: A density functional theory study

Asiye Shokri, Ahmad Yazdani, Kourosh Rahimi

MATERIALS CHEMISTRY AND PHYSICS (2020)

Article Materials Science, Multidisciplinary

Non-synthetic luminescent graphene quantum dots in coconut water for aniline sensing applications

A. Aly, M. Ghali, A. Osman, M. K. El Nimr

Summary: This study reports the discovery of naturally occurring luminescent graphene quantum dots (GQDs) in coconut water for the first time. The GQDs were identified through various measurements and were found to have dual sizes and emit different wavelengths of light. The GQDs were also utilized as an efficient optical sensor for aniline liquid detection.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

High-performance e-VOPO4 cathode materials for sodium ion battery applications

Zehua Chen, Wencheng Ma, Qinglu Fan, Yanhua Liu, Min Sun, Shuo Wang

Summary: The nanoscale e-VOPO4 materials were successfully prepared by hydrothermal synthesis and calcination, showing high purity and suitable particle size. It exhibited satisfactory electrochemical performance as cathode material for sodium ion batteries, making it a potential candidate for high energy storage systems.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Multifunctional terahertz device with active switching between bimodal perfect absorption and plasmon-induced transparency

Tao Liu, Yahui Liu, Le Ling, Zhongxi Sheng, Zao Yi, Zigang Zhou, Yongjia Yang, Bin Tang, Qingdong Zeng, Tangyou Sun

Summary: In this paper, a terahertz (THz) micronano device that can switch between bimodal absorption and plasmon-induced transparency (PIT) is proposed. The device consists of layers of graphene, silica, and vanadium dioxide, and has a simple structure, easy tuning, and wide-angle absorption. The device achieves perfect absorption at specific frequencies and is highly sensitive to environmental refractive index. It also has the functions of a three-frequency asynchronous optical switch and slow light effect.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Direct laser printing of 3D optical imaging based on full-spectrum solar-absorption-enhanced perovskite-type oxides

Xiaobo Luo, Songhan Hu, Qiudong Duan, Dacheng Zhou, Jialin Chen, Yugeng Wen, Jianbei Qiu

Summary: The exploration of solar light absorption by a material is important in photonics and optoelectronics. This study reveals the potential of Ba3-xGa2O6:xBi3+ as a promising candidate for various photonic and optoelectronic applications, and demonstrates the use of the material in double-sided laser printing for three-dimensional optical imaging.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Interface and magnetic-dielectric synergy strategy to develop Fe3O4-Fe2CO3/multi-walled carbon nanotubes/reduced graphene oxide mixed-dimensional multicomponent nanocomposites for microwave absorption

Hemin Wang, Yanling Hao, Lele Xiang, Xiaosi Qi, Lei Wang, Junfei Ding, Yunpeng Qu, Jing Xu, Wei Zhong

Summary: This study designed Fe3O4-FeCO3/MWCNTs/RGO MCNCs composites and fabricated large-scale samples using hydrothermal and freeze-drying methods. The microstructural investigation showed that these materials had a mixed-dimensional structure, which improved impedance matching features, polarization, and conduction loss abilities, leading to significantly enhanced electromagnetic absorption properties.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

All-dielectric terahertz metamaterial with polarization switching characteristic

Zhenshan Yu, Hao Chen, Xuequan Chen, Yu-Sheng Lin

Summary: This study presents a silicon dielectric metamaterial (SDM) composed of two outer symmetric semi-circular rings and two inner symmetric split-ring resonators (SRRs). The electromagnetic responses of the SDM device in different modes were studied through numerical simulations and experiments. Increasing the structure height of the SDM device resulted in red-shifted resonances and stronger intensities. This study provides a new design strategy for the development of frequency filtering, polarization switching, and resonance modulation characteristics in THz-wave applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

α-PW11Fe(Co/Ni)/BC derived carbon fiber based nanocomposites for high efficiency electromagnetic wave absorption via synergistic effects of polarization and conductance

Yiming Qi, Na Zhang, Meng Zong, Yangxianzi Liu, Weixing Chen

Summary: This study prepares dielectric/carbon fiber based nanocomposites wave-absorbing materials using liquid diffusion and high temperature carbonization strategies. By tuning the element type, drying mode, and filling amount, the electromagnetic parameters and absorbing properties can be adjusted. The best synthesized sample shows excellent absorbing performance, making it suitable for a wide range of electromagnetic wave absorption applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Study of the centers responsible for the TL emission by EPR and PL analysis of Eu-doped CaSiO3 phosphors synthesized by the devitrification method

Carlos D. Gonzales-Lorenzo, T. K. Gundu Rao, Alberto A. Ccollque-Quispe, Jorge Ayala-Arenas, Monise B. Gomes, Betzabel N. Silva-Carrera, Roseli F. Gennari, Valeria S. Pachas, F. Monzon-Macedo, H. Loro, Jose F. D. Chubaci, Nilo F. Cano, Rene R. Rocca, Shigueo Watanabe

Summary: In this study, CaSiO3 doped with different ppm of Eu was synthesized using the devitrification method. Various physical properties were analyzed, revealing that the intensity and temperature of the high-temperature TL peak increased with higher dopant amounts. Fluorescence measurements indicated the presence of Eu2+ and Eu3+ ions in the samples. EPR spectra confirmed the existence of two defect centers.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Synergetic assembly of a molybdenum disulfide/carbon quantum dot heterojunction with enhanced light absorption and electron transfer di-functional properties for photocatalysis

Yanning Qu, Xinyang Li, Mei Cui, Renliang Huang, Wanquan Ma, Yunting Wang, Rongxin Su, Wei Qi

Summary: In this study, a new molybdenum disulfide/N,S-doped carbon quantum dots (MoS2/N,S-CQDs) heterojunction with enhanced light absorption and electrons transfer di-functional properties was constructed via a facile one-pot hydrothermal method. The heterojunction showed remarkable efficiencies in degrading methylene blue (MB) and malachite green (MG) in an actual water system under simulated sunlight irradiation. The facile synthetic technique and effective multifunctional properties of the composite have the potential for further research and industrial applications.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Acid-alkali assisted synthesis of white tremella-like g-C3N4 homojunction for photocatalytic degradation under visible light

Jiayi Wang, Penggang Ren, Xueyan Zhao, Zhengyan Chen, Yanling Jin, Zengping Zhang

Summary: In this study, a novel homojunction photocatalyst was developed by combining defective g-C3N4 and flaked g-C3N4, which showed excellent degradation performance and cycling stability, and exhibited practicality in several simulation experiments.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Zn-MOF-derived hierarchical carbon nanorods superstructures with tunable microwave absorption properties

Jing Yan, Xiaoxiao Zhao, Weixing Chen, Panbo Liu

Summary: This research presents a self-templated strategy to prepare a spherical superstructure of carbon nanorods through material modification and pyrolysis. The resulting material exhibits a large controllable radius of curvature and shows excellent microwave absorbing properties due to its high specific surface area and mesoporous structure.

MATERIALS RESEARCH BULLETIN (2024)

Review Materials Science, Multidisciplinary

Electrolytes for liquid metal batteries

Qinglin Zeng, Zepeng Lv, Shaolong Li, Bin Yang, Jilin He, Jianxun Song

Summary: Liquid metal batteries possess stable safety performance, high rate performance, and thermal stability. The electrolyte, an important component of the battery, plays a significant role in achieving these remarkable performance characteristics. This paper reviews the important research progress of liquid metal batteries electrolyte and discusses the influence of different electrolyte types on energy efficiency. It also highlights the limitations and challenges of existing electrolytes and proposes key development directions for liquid metal electrolytes.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Mn3O4@C micro-flakes modified Ti/TiH2/β-PbO2 anode for accelerating oxygen evolution reaction in zinc electrowinning

Song Wu, Junli Wang, Xuanbing Wang, Di Jiang, Jinlong Wei, Xiaoning Tong, Zhenwei Liu, Qingxiang Kong, Naixuan Zong, Ruidong Xu, Linjing Yang

Summary: In this study, a composite electrode composed of Ti/TiH2/beta-PbO2_Mn3O4@C was fabricated and investigated for zinc electrowinning. The composite electrode exhibited low overpotential, Tafel slope, icorr, and high voltage stability, outperforming most reported Ti-based PbO2 electrode materials. The excellent catalytic activity can be attributed to the low resistance and porous interlayer of TiH2 nanosheets, as well as the addition of Mn3O4@C micro-flakes to the active layer.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Simulation study of a nanomaterial interacting with ionizing radiation through OTOR and IMTS models for different particle sizes

E. Tsoutsoumanos, T. Karakasidis, N. Laskaris, P. G. Konstantinidis, G. S. Polymeris, G. Kitis

Summary: This study investigates the correlation between nanocrystal dimensions and thermoluminescence signal magnitude through simulations conducted in Python. Two mathematical models, OTOR and IMTS, were used to derive theoretical luminescence signals. The obtained results were compared with experimental data and a thorough comparative discussion was conducted.

MATERIALS RESEARCH BULLETIN (2024)

Article Materials Science, Multidisciplinary

Enhanced photoresponsivity in Bi2Se3 decorated GaN nanowall network-based photodetectors

Vishnu Aggarwal, Sudhanshu Gautam, Aditya Yadav, Rahul Kumar, Bipul Kumar Pradhan, Brajesh S. Yadav, Govind Gupta, Senthil Kumar Muthusamy, Sumeet Walia, Sunil Singh Kushvaha

Summary: Recently, there has been a great demand for highly responsive photodetectors that can detect a wide range of wavelengths. Researchers have successfully fabricated a broadband metal-semiconductor-metal photodetector by integrating sputtered Bi2Se3 with laser molecular beam epitaxy grown GaN film. This photodetector shows high responsivity in both the ultraviolet and near-infrared regions.

MATERIALS RESEARCH BULLETIN (2024)