期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 24, 页码 7425-7428出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b03907
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资金
- U.S. Department of Energy (DOE), Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences, Heavy Element Chemistry program [DE-SC0004739, DE-AC52-06NA25396]
- Office of Workforce Development for Teachers and Scientists
- Office of Science Graduate Student Research (SCGSR) program [DE-AC05-06OR23100]
- Glenn T. Seaborg Institute
We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np2+ in [K(crypt)][(NpCp)-Cp-II ''(3)] [crypt = 2.2.2-cryptand, Cp '' = C5H3(SiMe3)(2)]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in the complex is Sf(4)6d(1).
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