期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 2, 页码 586-589出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b11591
关键词
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资金
- Scientific Research Program - Shaanxi Provincial Education Department [17JS129, 15JK1749]
- National Natural Science Foundation of China [NSFC 21502149, 21632003]
The nickel-catalyzed decarbonylation of unstrained diaryl ketones has been developed. The reaction is catalyzed by a combination of Ni(cod)(2) and an electron-rich N-heterocyclic carbene ligand. High functional group tolerance and excellent yields (up to 98%) are observed. This strategy provides an alternative and versatile approach to construct biaryls using an inexpensive nickel catalyst.
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