期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 23, 页码 7061-7064出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b03927
关键词
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资金
- European Research Council [ERC AdG 692775]
Both CO and N2O are important, environmentally harmful industrial gases. The reaction of CO and N2O to produce CO2 and N-2 has stimulated much research interest aimed at degradation of these two gases in a single step. Herein, we report an efficient CO oxidation by N2O catalyzed by a (PNN)Ru-H pincer complex under mild conditions, even with no added base. The reaction is proposed to proceed through a sequence of O-atom transfer (OAT) from N2O to the Ru-H bond to form a Ru-OH intermediate, followed by intramolecular OH attack on an adjacent CO ligand, forming CO2 and N-2. Thus, the Ru-H bond of the catalyst plays a central role in facilitating the OAT from N2O to CO, providing an efficient and novel protocol for CO oxidation.
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