期刊
JOURNAL OF POWER SOURCES
卷 379, 期 -, 页码 53-59出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.01.027
关键词
Lithium-ion battery; Oxide; Titania; Anode; Cathode; Sustainability
资金
- construct program of the key discipline in Hunan province (Applied Chemistry)
- Hunan Provincial Natural Science Foundation of China [2016JJ3094]
- Hunan Provincial Education Department [15C0933, 16C1082]
- Startup Foundation for Doctors of Hunan University of Arts and Science
- King Abdullah University of Science & Technology (Kingdom of Saudi Arabia)
- Natural Science Foundation of China [NSFC: 21703285]
Seeking advanced and safer lithium-ion battery with sustainable characteristic is significant for the development of electronic devices and electric vehicles. Herein, a new porous TiO2 nanobundles (PTNBs) is synthesized though a scalable and green hydrothermal strategy from the TiO2 powders without using any high-cost and harmful organic titanium-based compounds. The PTNBs exhibits an extremely high lithium storage capacity of 296 mAh g(-1) at 100 mA g(-1), where the capacity can maintain over 146 mAh g(-1) even after 500 cycles at 1000 mA g(-1). To pursue more reliable Li-ion batteries, full batteries of PTNBs/LiNixMn1-XO4 (x =0, 0.5) using spinet structured cathode are constructed. The batteries have the features of sustainability and deliver high capacities of 112 mAh g(cathode)(-1) and 102 mAh g(cathode)(-1) with stable capacity retentions of 99% and 90% over 140 cycles. Note that the energy densities can achieve as high as 267 and 270 Wh kgg(cathode)(-1) (535 and 540 Wh kg(anode)(-1)-1) respectively, which is feasible to satisfy diverse requirements for energy storage products. We believe that the universal synthetic strategy, appealing structure and intriguing properties of PTNBs is applicable for wider applications, while the concept of sustainable strategy seeking reliable and safer Li-ion battery can attract broad interest.
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