Article
Materials Science, Ceramics
Yuqing Han, Youqing Wu, Sheng Huang, Hong Zhang, Zijun Liang, Xuebo Guan, Shiyong Wu
Summary: By adjusting the alkali catalyst content, the hydrophobically modified silica aerogels using Dimethyldiethoxysilane (DDS) exhibit excellent structure and performance, making them suitable for harsh and humid environments.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2023)
Article
Materials Science, Ceramics
Xi Deng, Liling Wu, Yunmeng Deng, Siqi Huang, Mengtian Sun, Xiaowu Wang, Qiong Liu, Ming Li, Zhi Li
Summary: This study presents a simple synthesis method for MTES-based aerogels using pure water as the only solvent and investigates the effects of precursor concentration on physicochemical properties. The results show that precursor concentration does not affect chemical composition, but at lower concentrations, denser and slenderer skeletons are formed.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Engineering, Environmental
Selay Sert Cok, Fatos Koc, Nilay Gizli
Summary: This study demonstrated that silica aerogels modified with TMCS and MTMS exhibit good hydrophobicity, high adsorption capacity, and enduring adsorption property, making them promising candidates for oil/organic solvent clean up practices.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Polymer Science
Fabian Zemke, Julien Gonthier, Ernesto Scoppola, Ulla Simon, Maged F. F. Bekheet, Wolfgang Wagermaier, Aleksander Gurlo
Summary: Ambient pressure drying (APD) has the potential to reduce the cost of aerogel fabrication. This study investigates the effect of different silylation agents on the re-expansion of SiO2 aerogels after drying. The results show that while some physical properties were significantly affected by re-expansion, silylation did not always result in full re-expansion. The impact of silylation in tailoring the re-expansion behavior is crucial for APD of monolithic aerogels.
Article
Chemistry, Applied
Shengyuan Wang, Zhixiang Zhu, Ya Zhong, Jun Gao, Feng Jing, Sheng Cui, Xiaodong Shen
Summary: Hydrophobic SiO2 aerogels with superhydrophobic surfaces and low thermal conductivity are prepared using double silicon sources as co-precursors. The microstructure and chemical-physical properties of the aerogels treated at different temperatures are investigated. The TM and TE aerogels exhibit low thermal conductivity, high specific surface area, and good hydrophobicity, making them suitable for thermal insulation, catalysis, and environmental protection.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Agnieszka Slosarczyk
Summary: This study synthesized silica aerogel reinforced with short pitch carbon fibers from a cheaper precursor of water glass, resulting in improved mechanical and structural parameters of the composite. The presence of fibers in excess of 10% by volume also introduced a new function of the nanocomposite - the ability to conduct electric current.
Article
Engineering, Chemical
Yujing Liu, Xiao Han, Balati Kuerbanjiang, Vlado K. Lazarov, Lidija Siller
Summary: An economical ambient pressure drying method using sodium bicarbonate solution as the exchanging solvent was presented for preparing monolithic silica aerogels. The aerogels obtained had a density of 0.053 g/cm3 and a specific surface area of 423 m2/g, with an average pore diameter of 23 nm and a pore specific volume of 1.11 cm3/g. The aerogels exhibited a super-hydrophobic surface with a contact angle as high as 166 degrees under specific conditions.
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
(2021)
Article
Materials Science, Ceramics
Ying Chen, Je Kyun Lee
Summary: This study developed low-cost, lightweight, and low thermal conductivity pDCPD aerogels through simple sol-gel processing. The AP-dried pDCPD aerogels exhibited similar properties to supercritical CO2-dried pDCPD aerogels, making them a potential alternative to silica aerogel and other insulation materials.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Polymer Science
Sophie Groult, Sytze Buwalda, Tatiana Budtova
Summary: Porous pectin matrices, including cryogels, aerogels, and xerogels, were prepared using different drying methods in this study. The physico-chemical properties of these matrices and the release of theophylline were investigated. The results indicate that porous pectin matrices have great potential for drug delivery purposes.
EUROPEAN POLYMER JOURNAL
(2021)
Article
Engineering, Chemical
Xinxin Zhao, Wenlong Xu, Shuang Chen, Huie Liu, Xiaofei Yan, Yan Bao, Zexin Liu, Fan Yang, Huan Zhang, Ping Yu
Summary: The study successfully prepared a super elastic graphene aerogel through a simple preparation method, which has great potential for application in oil adsorption and environmental restoration. It exhibits highly repeatable performance and excellent adsorption capacity.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Applied
Wenpu Zhao, Yuecheng Ji, Yifan Pang, Xiaolei Li, Huiming Ji
Summary: In this study, Al2O3-SiO2 aerogel is prepared by ambient pressure drying method using inexpensive AlCl3 · H2O as a precursor, with silicon being deposited during the aging of aluminum gel. Ion exchange technology is used to remove chloride ions in the aluminum sol to explore their influence on the properties of ASA. ASA exhibits a low thermal conductivity at room temperature and shows enhanced thermal stability compared to the chlorine-containing aerogel. XRD and XPS analysis indicate that the removal of chloride ions hinders the formation of Al-O-Si groups during the aging process, preventing the transformation of gamma-Al2O3 and cristobalite phases to mullite phase. ASA has great potential for high-temperature applications in insulation, thermal protection materials, and building external wall thermal insulation.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Sheng Chen, Yanglei Chen, Deqiang Li, Yanglei Xu, Feng Xu
Summary: Renewable biomaterials like cellulose were used in the preparation of a composite aerogel for a flexible pressure sensor, exhibiting remarkable flexibility, fast response, and adjustable sensitivity in a wide pressure range. The sensor's working mechanism, potential applications, and the utilization of sustainable natural biomaterials in high-tech fields were well demonstrated in this study.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Applied
Uzma K. H. Bangi, Akshay A. Ransing, Rushikesh P. Dhavale, Hyung-Ho Park, Vikas B. Patil
Summary: Experimental work was conducted to enhance the properties of ambient pressure dried silica aerogels for thermal insulation applications. The quality of the aerogels produced was determined by the sol-gel method and silylating agent used. A two-step sol-gel method was employed to synthesize sodium silicate-based aerogels, with silylation carried out using trimethylchlorosilane (TMCS). The aerogels prepared using 33.3% TMCS exhibited desirable characteristics such as narrow pore size distribution, homogenous tiny particles, improved visual optical transmission, low density, low thermal conductivity, high specific heat capacity, high porosity, high surface area, and stable hydrophobicity up to 445°C. The thermal insulating property of these aerogels was confirmed in the laboratory, demonstrating their suitability for thermal insulation.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Materials Science, Ceramics
Zongwei Tong, Bixin Yan, Baojie Zhang, Hui Xu, Xiaolei Li, Huiming Ji
Summary: SiOC aerogels were prepared using sol-gel method and ambient pressure drying technology. The aerogels exhibited excellent properties with high porosity, high compressive strength, and low thermal conductivity. A new concept of gases truing was proposed to explain the microstructure evolution of the aerogels during pyrolysis, providing insights for the preparation of high-performance SiOC aerogels.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Yiting Liu, Mark Robertson, Zhe Qiang, Zheyi Meng, Changhuai Ye, Meifang Zhu
Summary: This study reports the fabrication of aerogels with layered structure and hierarchical nanopores based on aramid nanofibers using a low-cost ambient drying method. The ANF aerogels exhibit ultralow and tunable dielectric constants, high thermal stability, and flame retardancy. The presence of larger nanopores ensures high porosity and the overall aerogel film shows superior mechanical properties compared to conventional counterparts.
ACS APPLIED POLYMER MATERIALS
(2023)