Article
Engineering, Environmental
Maria J. Martin de Vidales, Esteban Palomo de la Fuente, Evangelina Atanes-Sanchez, Francisco Fernandez-Martinez
Summary: The aim of this study was to develop a new, highly compact multi-option photo reactor for the removal of emerging contaminants from wastewater. Different advanced oxidation processes, including electrochemical oxidation, photolysis, and photocatalysis with TiO2 nanotubes array, were investigated and combined to create a photoelectrocatalytic oxidation process. The efficiency of these processes was evaluated by measuring the removal of ofloxacin, a pharmaceutical compound used as a model contaminant. SEM and XRD characterization confirmed the formation of anatase-phase nanotubes with suitable dimensions for photocatalytic reactions. The results demonstrated that the coupling of these technologies was effective, leading to high process efficiencies.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Ana Rita Ferreira, Paula Guedes, Eduardo P. Mateus, Alexandra B. Ribeiro, Nazare Couto
Summary: This study investigated the electrochemical oxidation (EO) technology as an alternative tertiary treatment in wastewater treatment plants (WWTP) to remove contaminants of emerging concern (CECs) and Escherichia coli simultaneously. The results showed that the removal rate of CECs depended on their structure and physicochemical characteristics, as well as the electrode material and shape used. MMO with a higher surface area and circular-mesh electrode exhibited the highest removal efficiency for recalcitrant CECs (20-50%). Varying the current intensity had a minor effect on CECs removal. The overall removal efficiency of CECs exceeded 90% within 2 hours, with simultaneous removal of E. coli. The EO process was considered ecofriendly with a low estimated treatment cost of 1.1 euro/m3.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Chizoba I. I. Ezugwu, Jayesh M. M. Sonawane, Roberto Rosal
Summary: The pollution caused by contaminants of emerging concern (CECs) is a significant problem that poses a serious threat to human health and ecosystem functions. Metal-organic frameworks (MOFs) have emerged as a potential candidate for water and wastewater treatment. This review explores the application of MOFs for the removal of CECs, focusing on their redox-active properties and their use in advanced oxidation processes. The study also discusses the photocatalytic use of MOFs for removing dissolved emerging pollutants and provides an overview of future research directions.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Review
Geochemistry & Geophysics
Sebastien Ryskie, Carmen M. Neculita, Eric Rosa, Lucie Coudert, Patrice Couture
Summary: Responsible use and effective treatment of mine water are essential for sustainable mining. Contaminants of emerging concern present new challenges in mine water treatment, with a focus on addressing the specific treatment needs of mine sites operating in cold climates.
Article
Environmental Sciences
Liang Tang, Aozhou Li, Minghao Kong, Dionysios D. Dionysiou, Xiaodi Duan
Summary: Pollutants of emerging concern in aqueous environments pose a significant threat to the aquatic ecosystem and human health. UV-assisted advanced oxidation/reduction processes have been identified as competent and cost-effective treatment approaches for removing such pollutants. The effectiveness of these processes depends heavily on the wavelength of the UV irradiation used. This article systematically discusses the wavelength dependency of various UV-assisted processes on the transformation of contaminants and emphasizes the importance of matching the wavelengths with the target compounds and oxidants/reductants for optimized pollutant removal and disinfection byproduct control.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Engineering, Environmental
P. V. Nidheesh, Akeem Adeyemi Oladipo, Nael G. Yasri, A. R. Laiju, V. R. Sankar Cheela, Abdoulaye Thiam, Yemane G. Asfaha, S. Kanmani, Edward (Ted) P. L. Roberts
Summary: Electrocoagulation (EC) is known for its effectiveness in treating water and wastewater. Various improvements such as the addition of air and hydrogen peroxide to generate radicals, the use of an air cathode to reduce energy consumption, and the utilization of renewable energy sources have been adopted to enhance the applicability and performance of EC. It has been shown to be suitable for treating microplastics, nanoparticles, emerging contaminants, oil and grease, and disinfection.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2022)
Article
Engineering, Environmental
S. Guerra-Rodriguez, M. J. Abeledo-Lameiro, M. I. Polo-Lopez, P. Plaza-Bolanos, A. Aguera, E. Rodriguez, J. Rodriguez-Chueca
Summary: This study evaluates the effectiveness of four sulfate radical-based advanced oxidation processes (SR-AOPs) in removing microorganisms, contaminants of emerging concern (CECs), and antibiotic resistance genes (ARGs) in wastewater treatment plants. The PMS/O3 system is found to be the most effective treatment, while also exhibiting phytotoxicity.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Isabel Oller, Sixto Malato
Summary: The application of photo-Fenton technology in wastewater treatment is a popular research topic, especially in countries with water scarcity and abundant sunlight. Heterogeneous photo-Fenton processes working at neutral pH have gained attention, but designing efficient catalysts remains a major challenge.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2021)
Review
Environmental Sciences
Dariusz Kiejza, Urszula Kotowska, Weronika Polinska, Joanna Karpinska
Summary: There has been a growing interest in using advanced oxidation processes for water and wastewater decontamination, with new oxidants such as peracetic acid widely utilized. The degradation of organic compounds involves radicals derived from the activation of peracids, resulting in the formation of products of lower mass, less toxic, and more susceptible to biodegradation. The activation methods and matrix composition have a significant impact on the efficiency of contamination removal using peracids.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Review
Chemistry, Multidisciplinary
Saima Aftab, Tayyaba Shabir, Afzal Shah, Jan Nisar, Iltaf Shah, Haji Muhammad, Noor S. Shah
Summary: Water is vital for sustaining life, but only a small percentage is drinkable. Contaminants in water pose a serious threat to human and environmental health, and traditional treatment methods are often ineffective. Visible light active photocatalysts have shown promise in efficiently degrading water toxins.
Review
Environmental Sciences
Eduardo O. Marson, Cleiseano E. S. Paniagua, Oswaldo Gomes Junior, Barbara R. Goncalves, Valdislaine M. Silva, Ivo A. Ricardo, Maria Clara V. M. Starling, Camila C. Amorim, Alam G. Trovo
Summary: This work presents data on the occurrence and treatment of Contaminants of Emerging Concern (CECs) in Brazil in the past decade. The study reveals the detection of various pharmaceutical drugs, pesticides, hormones, illicit drugs, caffeine, and bisphenol A in different matrices. The inefficiency of conventional wastewater treatment methods and lack of basic sanitation contribute to the contamination of Brazilian aquatic environments and pose environmental and health risks. Advanced oxidation processes (AOPs) are considered viable alternatives to degrade CECs and prevent contamination. However, most studies evaluate the treatment of distilled water or simulated effluent, highlighting the importance of conducting studies in real matrices to drive the implementation of AOPs in water and wastewater treatment plants.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Environmental Sciences
Oksana Golovko, Stefan Orn, Mattias Sorengard, Kim Frieberg, Winnie Nassazzi, Foon Yin Lai, Lutz Ahrens
Summary: Wastewater treatment plants are major sources of Emerging Chemicals of Concern (CECs) in aquatic environments, impacting aquatic ecosystems. This study investigated 164 CECs at 15 locations, with CEC concentrations varying widely between WWTPs. The K-d of CECs correlated with K-ow, allowing for prediction of their distribution in water and solids. WWTP effluent had higher CEC concentrations than upstream waters, potentially impacting downstream ecosystems.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Environmental Sciences
P. M. Martins, Bruno Santos, H. Salazar, Sonia A. C. Carabineiro, G. Botelho, Carlos J. Tavares, S. Lanceros-Mendez
Summary: This work focuses on the combination of multifunctional photocatalytic and adsorbent materials in a unique polymeric membrane. The efficient functionalization of TiO2 nanoparticles with gold particles enabled absorption of visible radiation. The produced hybrid materials showed high efficiency in the degradation of norfloxacin and adsorption of arsenic, making them valuable for water treatment processes.
Review
Engineering, Environmental
Henrique Sousa, Catia A. Sousa, Lucia C. Simoes, Manuel Simoes
Summary: The study reviews the advantages and advances of using microalgae for wastewater treatment, highlighting the potential of using microalgae-bacteria biofilms for CECs removal and further biomass utilization for third-generation biofuel production.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Environmental Sciences
Marisa de Jesus Silva Chaves, Sergiane Caldas Barbosa, Ednei Gilberto Primel
Summary: Despite the presence of Contaminants of Emerging Concern (CECs) in the Brazilian environment, the biological effects on the aquatic ecosystem are still unknown, necessitating further research and monitoring. By analyzing data from the past decade, it was determined that 10 specific CECs pose the greatest threats to the Brazilian environment, urging for them to be prioritized in future monitoring studies. Identifying target monitoring compounds can aid in selecting pollutant candidates for future legislations.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)