期刊
JOURNAL OF PHYSICS D-APPLIED PHYSICS
卷 51, 期 4, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/1361-6463/aaa0ed
关键词
MAPbBr(3) single crystal; phase transitions; defects related photoluminescence
资金
- National Natural Science Foundation of China [11004009, 11404124]
- Opening Project of Wuhan National High Magnetic Field Center at Huazhong University of Science and Technology [2015KF14]
We investigated the fundamental properties of MAPbBr(3) single crystal by applying temperature-dependent x-ray diffraction and photoluminescence (PL) measurements from 10 K to 270 K. The structural and spectral analyses illustrate the phase transitions of MAPbBr(3) single crystal from cubic phase (alpha-M APbBr(3)) to tetragonal phases (beta-MAPbBr(3) and gamma-MAPbBr(3)), and then to orthorhombic phase ((delta-MAPbBr(3)) at similar to 230K,similar to 160K and similar to 150K, respectively. The Time-resolved PL results show tliat both free excitons (FE) and bound excitons (BE) have contributions to the PL emissions. The PL at high temperature mainly originates from the BE transitions, while the PL at low temperature ((delta-MAPbBr(3) phase) comes from both BE and FE transitions, and the FE related PL becomes more and more dominant at lower temperatures. The first-principle calculation at zero temperature reveals that the BE-related PL was caused by defects from the anti-site substitution of MA and Br ions.
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