期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 9, 期 5, 页码 1086-1091出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.8b00169
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资金
- LabEx PALM [ANR-10-LABX-0039-PALM]
- Vietnamese government
Methylviologen (MV2+) is perhaps the most used component as a reversible electron acceptor in photophysical studies. While MV2+ is most commonly implicated as a reversible one-electron mediator, its electrochemical properties clearly evidence two successive one-electron reduction processes. In this report, we have investigated on the light driven two-charge accumulation on MV2+ using a multicomponent system composed of the prototypical molecular photosensitizer [Ru(bpy)(3)](2+) and MV2+ in the presence of ascorbate as reversible electron donor. The sequential addition of two electrons on the methylviologen was tracked upon sequential excitation of the [Ru(bpy)(3)](2+) at optimized concentration of the electron acceptor. The charge accumulated state carries an energy of 0.9 eV above the ground state and has a lifetime of ca. 50 mu s. We have reached a fairly good global yield of approximately 9% for the two-charge accumulation. This result clearly demonstrates the potential of this simple approach for applications in artificial photosynthesis.
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