期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 364, 期 -, 页码 826-836出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2018.04.035
关键词
3D nanorod; 5% Ag/g-C3N4/Cu(BA); Photocatalytic degradation; Refractory pollutants; Kinetic studies
资金
- National Natural Science Foundation of China [51242001, 51572127, 5122351]
3-D composite materials containing nanorods of copper-biphenylamines framework at the exterior of Ag doped g-C3N4, to reduce colorless/refractory and colored organic contaminants, with prominent improvement in catalytic action was witnessed for 3-ID composite 5% Ag/g-C3N4/Cu(BA), in contrast to original g-C3N4. The improved samples forced electrons colonizing in upper CB and holes colonizing in lower VB, hence improving redox reaction supremacy of the charge carriers. 5% Ag/g-C3N4/Cu(BA) can easily degrade 100% to 99.5% of MO & RhB solutions in 60 min and 73% of phenol and 57% of TCP were degraded. Whereas the degradation efficacies of 5% Ag/g-C3N4/Cu(BN), 5% Ag/g-C3N4/Cu(PD), 5% Ag/g-C3N4 and g-C3N4 are inferior related to 5% Ag/g-C3N4/Cu(BA). The resilient dynamic reactive species (O-2(-), h(+), O-1(2), OH), directly caused mineralization of MO, RhB, phenol and TCP. The k(app) for 5% Ag/g-C3N4/Cu(BA) also showed superiority over other modified samples. The above results are advantageous for the expansion of a modified catalyst in a wholesale amount and its use. TEM, SEM, EDS elemental mapping, XRD, UV-vis, XPS, and VBXPS studies confirmed that Cu(BA) and 5% Ag/g-C3N4 display close communication with each other. This investigation delivers an innovative approach for extremely worthwhile composite photocatalyst enterprises for environmental remediation.
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