Article
Chemistry, Applied
Jiayi Yong, Jiazhen Chen, Yiqi Chen, Youlie Cai, Junkuo Gao
Summary: In this study, three Hofmann-type metal-organic frameworks with narrow pore size and high open metal sites density were reported for the selective separation of propylene from propane. Among them, NiNi-Pyz exhibited the best separation performance with high uptake and selectivity. Molecular simulations confirmed that the host-guest interactions in NiNi-Pyz were achieved through its slightly smaller pore size.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Engineering, Chemical
Mohamad Rezi Abdul Hamid, Yutian Qian, Ruicong Wei, Zhen Li, Yichang Pan, Zhiping Lai, Hae-Kwon Jeong
Summary: Metal-organic frameworks (MOFs) membranes hold great research value in gas separations, with zeoliticimidazolate frameworks (ZIFs) being the most widely studied. Other MOF membranes have also been researched for hydrogen purification and carbon capture. Engineering challenges such as cost, design, stability, and reproducibility are key considerations for the industrial scale-up of MOF membranes.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Review
Chemistry, Physical
Rebecca L. Siegelman, Eugene J. Kim, Jeffrey R. Long
Summary: Global investment in counteracting climate change has generated interest in carbon capture and sequestration (CCS) as an emissions mitigation technology. Porous materials can adsorb large quantities of gas, making them a promising solution for CO2 capture and decarbonization efforts.
Review
Chemistry, Multidisciplinary
Mohamad Rezi Abdul Hamid, Thomas Choong Shean Yaw, Mohd Zahirasri Mohd Tohir, Wan Azlina Wan Abdul Karim Ghani, Putu Doddy Sutrisna, Hae-Kwon Jeong
Summary: This paper presents the latest advances in ZIF membrane processing, focusing on their microstructural features and separation performance, while also providing prospects for future research directions.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Engineering, Chemical
Hae-Kwon Jeong
Summary: Metal-organic frameworks (MOFs) are a new class of nanoporous materials that have attracted significant research interest. They may provide unprecedented opportunities for producing ultrathin and tuneable molecular sieve membranes for gas separations.
Article
Chemistry, Multidisciplinary
Bhajan Lal, Karam B. B. Idrees, Haomiao Xie, Courtney S. S. Smoljan, Saman Shafaie, Timur Islamoglu, Omar K. K. Farha
Summary: We report the synthesis of a zinc-based MOF containing a three-dimensional (3D) linker, which shows high thermal stability for the separation of hexane isomers. The incorporation of the 3D linker enhances the structural stability and provides precise pore apertures/channels. This work represents a significant milestone in the construction of stable Zn-based MOFs and the incorporation of 3D linkers for challenging separations.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Nanoscience & Nanotechnology
Junsu Ha, Minji Jung, Jaewoo Park, Hyunchul Oh, Hoi Ri Moon
Summary: This study investigates Hofmann-type metal-organic frameworks (MOFs) for hydrogen isotope separation. The results show that Co(pyz)[Pd(CN)(4)] exhibits high selectivity and capacity, making it a promising material for practical applications in isotope separation.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Longlong Geng, Wenfeng Zhou, Xiaoli Wang, Tingting Li, Andrzej P. Nowak, Zhongmin Liu, Yong-Zheng Zhang, Da-Shuai Zhang, Xiuling Zhang, Haixiang Han
Summary: In this study, a decompression-thermalization strategy was used to tune the redox and catalytic hydrogenation properties of a Cu-containing metal-organic framework (MOF). The generation of open metal sites (OMSs) significantly improved the catalytic performance in hydrogenation reactions, with experimental and theoretical results showing that OMSs endow Cu species with unique electronic properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Chemistry, Physical
Shuyue Jia, Dongxiao Ji, Liming Wang, Xiaohong Qin, Seeram Ramakrishna
Summary: This review introduces the research progress in the fabrication of metal-organic framework (MOF) membranes, including the preparation of pure MOF membranes and the incorporation of MOFs into polymer matrix. Through the analysis of classic cases, the advantages and disadvantages of different preparation strategies and products are compared, providing general knowledge for the needs of different application scenarios. The important role that MOF membranes play in the applications of separation, adsorption, and catalysis is highlighted, along with the opportunities and challenges in this new era.
Article
Chemistry, Multidisciplinary
Hoai T. B. Pham, Ji Yong Choi, Shaofeng Huang, Xubo Wang, Adam Claman, Michael Stodolka, Sadegh Yazdi, Sandeep Sharma, Wei Zhang, Jihye Park
Summary: The development of 2D electrically conductive metal-organic frameworks (EC-MOFs) has expanded the applications of MOFs. This study presents a new EC-MOF with a large surface area, high electrical conductivity, and tunable particle size. The framework also utilizes functional groups to host heterometal ions, providing new opportunities for expanding the library of EC-MOFs and exploring electronic applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Febrian Hillman, Mohamad Rezi Abdul Hamid, Panagiotis Krokidas, Salvador Moncho, Edward N. Brothers, Ioannis G. Economou, Hae-Kwon Jeong
Summary: The delayed linker addition (DLA) synthesis strategy allows for efficient incorporation of Im linkers into ZIF-8 framework, improving gas separation performance. The Im/ZIF-8 synthesized via DLA demonstrates outstanding performance in gas separation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Analytical
Lei Zhu, Jianan Wang, Jianwei Liu, Zhicheng Xu, Muhammad Salman Nasir, Xin Chen, Ze Wang, Shiyi Sun, Qianyue Ma, Jinbo Liu, Jiangtao Feng, Jidong Liang, Wei Yan
Summary: The current gas sensors suffer from insufficient sensitivity and selectivity, limiting their application in real-time monitoring of low concentration gas. This study proposes a versatile in situ enrichment amplification strategy that effectively enhances the detection sensitivity and selectivity of gas sensors for hazardous trace gases.
SENSORS AND ACTUATORS B-CHEMICAL
(2022)
Article
Chemistry, Multidisciplinary
Petru Apostol, Sai Manoj Gali, Alice Su, Da Tie, Yan Zhang, Shubhadeep Pal, Xiaodong Lin, Vasudeva Rao Bakuru, Darsi Rambabu, David Beljonne, Mircea Dinca, Alexandru Vlad
Summary: Two-dimensional electrically conducting metal-organic frameworks (2D-e-MOFs) are a promising class of functional materials with various applications. This study reports two isostructural 2D-e-MOFs that can be chemically functionalized and exhibit temperature-activated charge transport.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Nikita Hanikel, Daria Kurandina, Saumil Chheda, Zhiling Zheng, Zichao Rong, S. Ephraim Neumann, Joachim Sauer, J. Ilja Siepmann, Laura Gagliardi, Omar M. Yaghi
Summary: A linker extension strategy is proposed to generate metal-organic frameworks (MOFs) with enhanced moisture-capturing properties. The design approach results in MOF-LA2-1 {[Al(OH)(PZVDC)], featuring a 50% increase in water capacity compared to MOF-303, the state-of-the-art water-harvesting material. The strategy not only increases the pore volume of the MOF, but also retains its ability to capture and release water in arid environments, while reducing regeneration heat and temperature.
ACS CENTRAL SCIENCE
(2023)
Article
Chemistry, Inorganic & Nuclear
Bin Tan, Xing-Wu Liu, Hao Wang, Guo-Yu Yang, Jie Zhang
Summary: This study develops an efficient gas separation adsorbent based on porous materials, which can effectively remove carbon dioxide from natural gas and separate hydrocarbons. The material shows selective adsorption to CO2 and C2H2 through the use of specific ligands and cationic groups. The separation mechanism is revealed, providing specific guidance for the design of porous materials for energy resource purification.
DALTON TRANSACTIONS
(2022)
Article
Engineering, Environmental
Heseong An, Kie Yong Cho, Seungho Yu, Ki Chul Kim, Ju Ho Shin, Ki Jin Nam, Jung Hoon Park, Jong Suk Lee
Summary: A new class of highly CO2 selective ZIF nanoparticles, TAZIF-8, has been reported, and their physical structure and textural properties can be fine-tuned for enhanced CO2 separation performance.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Ji Min Han, Sang Eun Yoon, Ku Hyun Jung, Onyu Bae, Donguk Kim, Unjeong Kim, Hyungtak Seo, Felix Sunjoo Kim, Ki Chul Kim, Jong H. Kim, Bong-Gi Kim
Summary: This study synthesized a new conjugated polymer with efficient doping using both electron acceptor and Lewis acid type dopants, achieving high electrical conductivities. The interaction between the electron-donating atoms in the doped polymer and the dopants influenced the conductive properties and stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Jae Won Choi, Seokhee Shin, Soo Youp Park, Pil-Sang Youn, Seungho Yu, Daewook Kim, Jeong-Hoo Choi, Ki Chul Kim
Summary: This study examines the fouling behavior of CO2 absorbent particles in fluidized beds and identifies the key parameters that affect absorbent fouling. The results show that the cooling water temperature, riser temperature, air velocity, and relative humidity are crucial factors in the fouling conditions.
CHEMICAL ENGINEERING & TECHNOLOGY
(2022)
Article
Engineering, Chemical
Jae Won Choi, Yo-Sep Min, Ki Chul Kim
Summary: This study utilizes density functional theory modeling to investigate the ALD half-cycle mechanisms of O3-dosed Al2O3 metal oxide films. Three different schemes were studied, revealing the reaction steps between oxygen and aluminum groups. The relative feasibility of the two key competitive steps was analyzed, showing that the competitors and final selection depend on the process conditions.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Engineering, Environmental
Jaegwan Shin, Minhee Choi, Chae Young Go, Sungjun Bae, Ki Chul Kim, Kangmin Chon
Summary: In this study, NaOH-assisted H2O2 post-modification was proposed as a novel strategy to enhance the adsorption of radioactive strontium (Sr) onto residual coffee waste biochars (RCWBs). The highest adsorption capacity of Sr(II) was achieved by NaOH-assisted H2O2 post-modified RCWBs, which can be attributed to the increased negative surface zeta potential and decoration of Na on the surfaces of the biochars. The findings suggest that NaOH-assisted H2O2 post-modification is a practical approach to improve the adsorption capacity of Sr(II) using RCWB-based carbonaceous adsorbents in real water matrices.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Hoyoung Lee, Sohee Lim, Ki Chul Kim
Summary: In this study, TCNQ and F4TCNQ derivatives with aromatic and cumulene backbones were designed to improve the structural durability and electrochemical properties of macromolecular sodium-ion battery cathode materials. The presence of odd and even cumulene chains affected the electrochemical and structural characteristics. For even cumulenes, the inductive effect increased with increasing chain length, leading to an increase in the intrinsic redox potential. In the case of odd-numbered cumulene skeletons, the sequential Na binding near the redox-active cyanides was preferred, thereby enhancing cyclic stability. A structurally durable [9]F4TCNQ unit with exceptional electrochemical performance was designed by combining the electron-withdrawing characteristics of fluorine and the intrinsic nature of the odd-numbered cumulene skeleton.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Siku Choi, Songi Song, Yeongnam Ko, Ki Chul Kim
Summary: This study investigates the effects of the redox-active site type and the bridging style on the structural integrity and intrinsic redox activity of organic complexes. The findings provide insights for the design of insoluble organic cathode materials that can sustain high performance and structural durability.
Article
Materials Science, Multidisciplinary
Hyungu Han, Chae Young Go, Ki Chul Kim
Summary: This study systematically explores the structural, electronic, and electrochemical properties of a series of transition metal-doped, Li-excessive, layered Li2NiO2 materials. The incorporation of Cr dopant with electronically suitable d orbitals is revealed to be the best choice to design high-voltage Li2NiO2 cathode materials with little sacrifice of energy density and structural stability. Further investigation highlights that the d-orbital based design of a proper dopant would be a key strategy to develop Li2NiO2-based cathode materials with high-performance battery applications.
CURRENT APPLIED PHYSICS
(2023)
Article
Engineering, Chemical
Jeong Pil Kim, Chae Young Go, Junhyeok Kang, Yunkyu Choi, Ju Yeon Kim, Jiwon Kim, Ohchan Kwon, Ki Chul Kim, Dae Woo Kim
Summary: Nanoporous multilayer graphene oxide membranes were fabricated to achieve Li-ion selectivity. The influence of interlayer spacing and nanopore presence on ion separation performance was investigated. The NMG membrane showed different ion permeance depending on ion concentration, with faster permeation rate of divalent ions and Li-ion selectivity at high ionic strength.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Materials Science, Ceramics
Do -Young Go, Dae-Han Lee, Dong-Geun Lee, Jae Seung Seol, Ki Chul Kim, Sungki Lim
Summary: Cesium-doped BASEs were prepared to improve the wettability of molten sodium in Na/NiCl2 batteries. The properties, such as ionic conductivity, were studied. The addition of cesium affected the crystal phase formation, relative sintered density, and ionic conductivities.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Multidisciplinary Sciences
Junhyeok Kang, Yeongnam Ko, Jeong Pil Kim, Ju Yeon Kim, Jiwon Kim, Ohchan Kwon, Ki Chul Kim, Dae Woo Kim
Summary: Layered two-dimensional materials with interlayer structures can be used for organic solvent nanofiltration (OSN) membranes due to their precise molecular sieving ability and stability in harsh conditions. In this study, nanoporous graphene (NG) with a high density of sp(2) carbon domains was synthesized by microwave treatment and showed ultrafast organic solvent permeance and excellent stability. The membrane's molecular weight cut-off (MWCO) can be switched depending on the solvent type, allowing for the separation of multiple organic mixtures using a single membrane.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Min Kyu Choi, Ki Chul Kim
Summary: In this study, a reliable prediction protocol for the dielectric strengths of a broad array of perfluorocarbon (PFC) and non-PFC compounds is developed through the combination of systematic linear regression and computational calculations of relevant core factors. The core factors include polarizability, molecular weight, ionization energy, and HOMO-LUMO gap.
APPLIED SCIENCES-BASEL
(2023)
Article
Engineering, Environmental
P. Anil Kumar Reddy, Hyungu Han, Ki Chul Kim, Sungjun Bae
Summary: We synthesized a nanocomposite of 2D reduced graphene oxide (rGO) and 3D graphitic carbon (gC) embedded CoS2@gC/rGO as an anode material for supercapacitors. The composition of the composite was controlled by changing the calcination temperatures of the rGO sandwiched ZIF-67. The CoS2@gC/rGO composite exhibited high specific capacitance and cyclic stability, and was used to fabricate an all-solid-state asymmetric supercapacitor device with excellent performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Songi Song, Ki Chul Kim
Summary: This study investigates the structural stability and thermodynamic degradation probabilities of selected fluorocarbon compounds as alternative insulating gases. It reveals that these compounds are suitable insulation candidates under vacuum conditions, but the presence of specific impurity gases may compromise their stability.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
Jae Seung Seol, Seungho Yu, Ki Chul Kim
Summary: Despite the broad range of inorganic cathode materials developed to date, there is a lack of studies on the correlation between the electronic structure and performance. This study suggests that the symmetricity/asymmetricity of e(g)/t(2g) orbitals in redox-active elements is crucial in determining the Jahn-Teller distortion of LiM0.125Mn1.875O4 spinel-type cathode materials. The presence of Mn3+ ions during the discharging process leads to poor structural durability and electrochemical performance, and this limitation can be overcome by adding carefully selected Ni2+ dopants.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Guojun Hu, Ziyue Deng, Yanwei Wang, Dan Yuan, Yong Zhang, Yingming Yao
Summary: A series of rare-earth metal complexes were synthesized and used as efficient initiators for the polymerization of trimethylene carbonate (TMC) and (L)-lactide ((L)-LA).
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Van Ha Nguyen, John H. K. Yip
Summary: In this study, eight PtII-azulene complexes were synthesized to investigate the effect of metalation on the electronic structures, spectroscopy, and luminescence of organic chromophores. The results showed that the attachment of Pt substituents to azulene affected the HOMOs, LUMOs, and luminescence properties. The study provides insights into the role of metalation in modifying the properties of organic chromophores.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Moon Kedia, Virender Singh, Bhaskaran Shankar, Malaichamy Sathiyendiran
Summary: This study synthesized two types of neutral binuclear metallocycles using a one-pot solvothermal method and characterized their structures. The analysis revealed that these complexes adopt a binuclear heteroleptic cyclic architecture and belong to phosphine oxide donor (P=O)-based supramolecular coordination cyclic complexes.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Radhey S. Srivastava
Summary: This study demonstrates the effectiveness of zero-valent elements as reductants for the deoxydehydration reaction of polyols catalyzed by ONO-pincer ligated molybdenum dioxo. The insolubility and easy separability of the reductants and their oxidized products during the reaction are emphasized. Additionally, the choice of ligand has an impact on the catalytic performance of the reaction.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Hao Zhou, Yajun Sun, Li Deng, Weiran Yang, Yuehui Li
Summary: Efficient Ru-catalyzed hydrogenation of aldehydes was achieved using carbazole-derived phosphine ligands, with the crucial role of N-H moiety in promoting the catalytic reaction. The method was successfully applied in the Co/Ru-catalyzed hydroformylation process, resulting in the production of long-chain alcohols with excellent yields.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Theodor Danescu, Alexandru Lupan, Radu Silaghi-Dumitrescu, R. Bruce King
Summary: The structures and energies of complexes containing (Me2C2N2P)2Ru2(CO)n and (Me2C2N2P)2Fe2(CO)n have been studied. Low-energy structures are characterized by the presence of bridging diazaphospholyl rings, while higher-energy structures involve different ligand structures.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Savannah C. Kapper, Aamani Ponnekanti, Jonas Schaab, Tian-yi Li, Christine L. Chung, Gael Ung, Peter I. Djurovich, Mark E. Thompson
Summary: Organometallic iridium complexes with two cyclometalated ligands and one bis-oxazoline derived ancillary ligand were studied. These complexes have emission spanning across the visible and near-ultraviolet region, with moderate to high photoluminescence quantum yields. The (ppy)2Ir(BOX-CN) complexes were resolved into Delta- and Lambda-diastereomers based on solubility differences.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zahra Karimi Sangari, Hossein Naeimi
Summary: In this research, a nanostructured CoCuFe2O4 catalyst was prepared using a brief and useful synthetic strategy. This catalyst was used for synthesizing 1,2,4,5-tetrasubstituted imidazole derivatives under ultrasonic irradiation. The approach offers advantages such as high efficiency, short reaction times, simplicity of the reaction medium, accelerated reaction rates, and easier separation and purification of products.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rukhsana Gul, Wajid Munir, Ebraheem Abdu Musad Saleh, Shaukat Shujah, Muhammad Sirajuddin, Saira Tabassum, Khalil Ur Rehman, Dilfaraz Khan, Sameerah I. Al-Saeedi, Ehab A. Abdelrahman
Summary: Two new Schiff base ligands were synthesized and used to form copper, nickel, and cobalt complexes. The synthesized compounds were characterized and screened for various biological activities. The metal complexes showed better activities in antibacterial, antifungal, antidiabetic, and antioxidant assays.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Review
Chemistry, Inorganic & Nuclear
Ahsan Nazir, Pengwei Huo, Ameena Tur Rasool
Summary: This review explores the potential of g-C3N4-based S-scheme heterojunctions in addressing environmental issues. It summarizes the mechanism and preparation techniques of S-scheme heterojunctions based on g-C3N4, and presents recent studies on their applications in pollutant removal, CO2 reduction, hydrogen production, and bacterial disinfection. The review concludes with an outlook on future challenges for g-C3N4-based S-scheme heterojunctions.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Francois Mazars, Koffi Senam Etse, Guillermo Zaragoza, Lionel Delaude
Summary: The activity of three Pd-PEPPSI catalyst precursors with N-heterocyclic carbene (NHC) ligands derived from caffeine and theophylline in Mizoroki-Heck reactions was tested. The results showed that the catalysts achieved high conversions and yields, especially in the presence of electron-withdrawing substituents.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Bo-Han Wu, Xue Zhou, Lin Liu, Zheng-Bo Han
Summary: Researching carbon dioxide removal from flue gas and natural gas is crucial. Metal-organic frameworks (MOFs) are commonly used in adsorption due to their high surface area, porosity, and chemical properties. An ultra-microporous MOF CPM-20(Co) with mixed ligand was synthesized using inexpensive ligands. The material exhibited high selectivities and low regenerative energy, making it a promising option for CO2 separation in industries.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2024)