期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 15, 页码 7574-7585出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01307
关键词
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资金
- Sao Paulo Research Foundation FAPESP [2018/00106-7, 2015/21110-4, 2013/07276-1, 2011/13993-2]
- CNPq, National Council of Science and Technology, Brazil
- CAPES, Ministry of Education
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [15/21110-4] Funding Source: FAPESP
We have investigated the continuous flow photo oxidation of several conjugated dienes and subsequent rearrangement using a practical and safe continuous-flow homemade engineered setup. End-to-end approaches involving endoperoxidation, Kornblum-DeLaMare rearrangement, and additional rearrangements are comprehensively detailed with optimization, scope, and scale-up to obtain useful hydroxyenones, furans, and 1,4-dicarbonyl building blocks.
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