Article
Mechanics
Alice Briole, Laura Casanellas, Marc-Antoine Fardin, Charlotte Py, Olivier Cardoso, Julien Browaeys, Sandra Lerouge
Summary: In this study, the response of semidilute shear-banding wormlike micelles to time-dependent flow protocols was reported. It was shown that the onset of banding is delayed and transients are longer when stress is used as a control parameter, and the way the banding structure is built up strongly depends on the control parameter. Additionally, secondary flows develop on top of the shear-banding instability in both cases, leading to different dynamics in the flow structure.
JOURNAL OF RHEOLOGY
(2021)
Article
Polymer Science
Sebastien Roland, Guillaume Miquelard-Garnier, Andrey V. Shibaev, Anna L. Aleshina, Alexis Chenneviere, Olga Matsarskaia, Cyrille Sollogoub, Olga E. Philippova, Ilias Iliopoulos
Summary: Dual transient networks were prepared by mixing highly charged long wormlike micelles of surfactants with polysaccharide chains of hydroxypropyl guar above the entanglement concentration for each of the components. The system exhibited macroscopic homogeneity over a wide range of polymer and surfactant concentrations, but microphase separation was observed with the formation of polymer-rich and surfactant-rich domains.
Article
Chemistry, Physical
Ricky F. Lopez-Santiago, Jorge Delgado, Rolando Castillo
Summary: This study investigates the influence of elastic forces on the rheological behavior of wormlike micellar solutions through various experimental methods. The findings highlight the significance of the entanglement index in understanding the origin of elastic forces.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Polymer Science
Xiaohui Su, Zhiguo Wang, Jialun Liu, Song Wu
Summary: In this study, the flow dynamics of wormlike micellar solutions around a sphere in the creeping flow regime were investigated numerically. It was found that there exists a region with a high velocity in the wake of the sphere when the fluid flows past a sphere at very low Reynolds numbers. The results indicate that the elasticity of the fluid causes the flow instability at low Reynolds numbers, and the increase in the elasticity enhances the chaos of the velocity fluctuation.
Article
Chemistry, Multidisciplinary
Trang Vu, Geoffrey Reynolds, Howard D. Hutton, Gerald B. Kasting, Peter Koenig
Summary: The study investigated the effect of nonionic cosurfactants on thickening mechanism in a mixture of an amino acid-based surfactant and a zwitterionic cosurfactant, revealing that nonionic cosurfactants can significantly increase viscosity and alter the pH at which viscosity maximum occurs.
Article
Chemistry, Physical
Dongmei Lv, Qi Liu, Chenyong Wang, Huijun Wu, Na Zhao, Baolin Yin, Xilian Wei, Jing Li
Summary: This study presents a novel dual-stimuli triggered wormlike micellar solution prepared by mixing cationic surfactants and sodium hydrogen phthalate. The solution can switch between a water-like state and a gel-like state by adjusting the pH and temperature. The change in flowing behavior is attributed to the microstructural transition between different micellar structures.
Article
Chemistry, Multidisciplinary
Emad Jafari Nodoushan, Young Ju Lee, Hae-Joong Na, Byoung-Hee You, Moo-Yeon Lee, Namwon Kim
Summary: The addition of NaCl reduces the viscosity of wormlike micellar solutions, leading to the formation of branch points that result in shorter relaxation times and lower zero-shear viscosity.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Chemistry, Physical
Dongmei Lv, Qi Liu, Huijun Wu, Yiyao Cheng, Chenyong Wang, Baolin Yin, Xilian Wei, Jing Li
Summary: This study prepared a novel multi-stimuli responsive wormlike micellar solution by mixing a cationic surfactant and trans-o-hydroxycinnamic acid, and investigated the system's structure and viscoelasticity regulation by pH, temperature, and light irradiation. Results showed the transformation of spherical micelles to wormlike micelles and short micelles, and demonstrated the reversible alteration of microstructure by adjusting pH. The study provides insights into the transformation mechanism and multi-responsive properties of the wormlike micellar system.
Article
Chemistry, Multidisciplinary
Wenxiu Liu, Yaqin Wang, Yue Tan, Zhicheng Ye, Qizhou Chen, Yazhuo Shang
Summary: This study constructed a pH and UV light dual stimuli-responsive system with abundant self-assembly behaviors and adjustable rheological properties. The results show that multiple ionization and photo-isomerization enable the system to respond richly to pH and UV light stimuli.
Article
Mechanics
A. Haque, A. K. Nayak, Bernhard Weigand
Summary: This article presents a mathematical study on electroosmotic flow of power law fluids driven by an external electric field, created by multiple wavy triangular modulated polarized wall hurdles in microslits. The study demonstrates that geometric modification and potential heterogeneity play key roles in enhancing mixing efficiency through fluid folding and stretching.
Article
Chemistry, Physical
Duccio Tatini, Martina Raudino, Moira Ambrosi, Emiliano Carretti, Irina Davidovich, Yeshayahu Talmon, Barry W. Ninham, Pierandrea Lo Nostro
Summary: This study investigated the structural, thermal, and rheological properties of a moderately concentrated (13% w/w) dispersion of sodium oleate in water for the first time. The results showed significant deviations in the phase and rheology behavior of the surfactant at this concentration, with the addition of small amounts of KCl causing a transition from elongated wormlike micelles to a gel-like viscous material. These viscoelastic aqueous dispersions of NaOL are considered excellent candidates for stimuli-responsive green materials, with their behavior depending on the presence of cosolutes such as KCl.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Mechanics
Ole Hassager, Yanwei Wang, Qian Huang
Summary: Polymeric liquid bridges are prone to failure during extension, but a steady extensional viscosity can still be measured under specific conditions. Additionally, reliable stress measurements can be obtained during a relaxation phase. Various constitutive equations were simulated to draw these conclusions.
Article
Chemistry, Physical
K. B. Shishkhanova, V. S. Molchanov, A. N. Baranov, E. P. Kharitonova, A. S. Orekhov, N. A. Arkharova, O. E. Philippova
Summary: Soft viscoelastic nanocomposites were prepared by incorporating aluminosilicate clay halloysite nanotubes into the network of entangled linear wormlike micelles. The nanotubes were shown to increase the viscosity by attaching to the micellar endcaps. Cryo-TEM visualization confirmed the junctions between the micelles and the nanotubes. The nanocomposites exhibited peculiar flow curves with two shear thinning regions and a plateau, and their viscosity was pH responsive, increasing by 30 times with increasing pH from 4 to 9 due to the interaction between the nanotubes and oppositely charged micelles.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Physics, Condensed Matter
Antonio Tavera-Vazquez, Natalia Rincon-Londono, Ricky F. Lopez-Santiago, Rolando Castillo
Summary: This review paper presents a procedure for measuring the mesoscopic scales in micellar solutions embedded with giant cylindrical micelles. The method involves using the mean square displacement determined with a quasi-elastic multiple light scattering method and theory. The paper evaluates the whole procedure, including the performance of the scattering experiments, recovery of optical parameters, and the development of micro-rheology for obtaining the mesoscopic scales in these complex fluids.
JOURNAL OF PHYSICS-CONDENSED MATTER
(2022)
Article
Chemistry, Multidisciplinary
Wenxiu Liu, Zhicheng Ye, Qizhou Chen, Xiangrong Huang, Yazhuo Shang, Honglai Liu, Hong Meng, Yifan He, Yinmao Dong
Summary: This study investigated the effects of different methoxy substituent positions on the phase behavior and UV light-responsive behavior of mixed systems of cationic surfactant and photosensitive additives. The interaction energies and molecular properties were calculated to analyze the differences in phase behaviors. The photo-responsive behaviors of the wormlike micelle solutions were studied using rheological methods and spectroscopy, revealing the decisive role of reaction rates in photosensitivity. This research provides insights into UV light-responsive mechanisms at the molecular level and offers guidance for the preparation of smart materials with adjustable light sensitivity.
Article
Mechanics
Michael Cromer, L. Pamela Cook
JOURNAL OF RHEOLOGY
(2016)
Article
Mechanics
Joseph D. Peterson, Michael Cromer, Glenn H. Fredrickson, L. Gary Leal
JOURNAL OF RHEOLOGY
(2016)
Article
Mechanics
Michael Cromer, Glenn H. Fredrickson, L. Gary Leal
JOURNAL OF RHEOLOGY
(2017)
Article
Physics, Fluids & Plasmas
Arthur Kalb, Larry A. U. Villasmil, Michael Cromer
PHYSICAL REVIEW FLUIDS
(2017)
Article
Engineering, Chemical
Michael Cromer, L. Pamela Cook, Gareth H. McKinley
CHEMICAL ENGINEERING SCIENCE
(2009)
Article
Mechanics
Michael Cromer, L. Pamela Cook, Gareth H. McKinley
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS
(2011)
Article
Mechanics
Michael Cromer, L. Pamela Cook, Gareth H. McKinley
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS
(2011)
Article
Mechanics
Michael Cromer, Michael C. Villet, Glenn H. Fredrickson, L. Gary Leal, Roman Stepanyan, Markus J. H. Bulters
JOURNAL OF RHEOLOGY
(2013)
Article
Mechanics
Michael Cromer, Michael C. Villet, Glenn H. Fredrickson, L. Gary Leal
Article
Mechanics
Michael Cromer, Glenn H. Fredrickson, L. Gary Leal
Article
Biochemistry & Molecular Biology
Kenneth Reed, Nathan Bush, Zachary Burns, Gwendolyn Doherty, Thomas Foley, Matthew Milone, Kara L. Maki, Michael Cromer
Article
Chemistry, Multidisciplinary
Brian Wojcik, Jason LaRuez, Michael Cromer, Larry A. Villasmil Urdaneta
Summary: Increasing Reynolds number and Weissenberg number, or decreasing viscosity ratio, leads to larger vortices. Depending on the combination of polymer viscosity ratio and elasticity number, vortices may form either upstream (driven by elasticity) or downstream of the bend (driven by inertia), or be suppressed.
APPLIED SCIENCES-BASEL
(2021)
Article
Mechanics
Kimberlee S. M. Keithley, Jacob Palmerio, Hector A. Escobedo, Jordyn Bartlett, Henry Huang, Larry A. Villasmil, Michael Cromer
Summary: In flows with re-entrant corners, polymeric fluids can form recirculation regions called lip vortices. The formation of these vortices is controlled by the material's extensional and shear rheology. Elasticity is a necessary element for the formation of these lip vortices, and their onset and size are determined by the degree of shear thinning and the critical shear rate.
Article
Physics, Fluids & Plasmas
Joseph A. Green, Daniel J. Ryckman, Michael Cromer
Article
Mechanics
Mateus C. Guimaraes, Fernando T. Pinho, Carlos B. da Silva
Summary: A new theory is proposed to describe the conformation state of polymer chains in free turbulent shear flows of viscoelastic fluids. The theory shows the existence of minimum and maximum solvent dissipation reduction asymptotes and four different polymer deformation regimes, based on self-similarity arguments and new scaling relations for the turbulent flux of conformation tensor. In addition, analytical solutions for the self-similar transverse profiles of the conformation tensor components are obtained. The theory is validated through excellent agreement with direct numerical simulations employing the FENE-P rheological model.
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS
(2024)