Review
Energy & Fuels
Jiani Wang, Hailong Wang, Songyan Jia, Qin Zhao, Qiang Zheng, Yali Ma, Tianyi Ma, Xue Li
Summary: Lithium-sulfur (Li-S) batteries have a higher theoretical capacity and several advantages compared to lithium-ion batteries. However, issues like the shuttle effect of polysulfide and degradation of cycle stability hinder their practical application. Functionalized membranes offer a key approach to address these challenges. Recent research has focused on mitigating the shuttling effect and improving cycle stability through membrane functionalization. This paper provides a comprehensive review of recent progresses and predicts future research trends in this area.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Nanoscience & Nanotechnology
Qian Li, Yasai Wang, Yang Wang, Liwen Yang, Yanxiao Chen, Xiaodong Guo, Zhenguo Wu, Benhe Zhong, Wei Xiang
Summary: The use of molybdenum dioxide coated with carbon composite (MoO2@C) as a coating on the separator of lithium-sulfur batteries can significantly improve the battery's electrochemical performance by reducing the loss of active substances through the synergistic effect of physical barrier and chemical adsorption.
Article
Chemistry, Physical
Zhihang Fang, Long Tu, Zhijia Zhang, Jiankun Wei, Yinyu Xiang, Wei Guo, JunSheng Li
Summary: Researchers have successfully fixed a thermal stable bacterial cellulose (BC) separator with polyethyleneimine (PEI) to form a solid electrolyte interface with high ionic conductivity. This separator effectively inhibits lithium dendrite growth and polysulfide shuttling, leading to improved cyclic stability and rate performance in lithium-sulfur batteries.
APPLIED SURFACE SCIENCE
(2022)
Review
Biochemistry & Molecular Biology
Bo-Wen Zhang, Bo Sun, Pei Fu, Feng Liu, Chen Zhu, Bao-Ming Xu, Yong Pan, Chi Chen
Summary: Lithium-sulfur batteries are promising energy storage devices with high energy density, but the shuttle effect of polysulfide intermediates limits their commercial applications. The electrochemical performance of lithium-sulfur batteries can be improved by rational design of the separator. This review summarizes the research progress in modifying lithium-sulfur battery separators from the perspectives of adsorption effect, electrostatic effect, and steric hindrance effect, and prospects a novel modification method.
Article
Engineering, Environmental
Xiaofei Wang, Dawei Lan, Jun Li, Zhendong Wang, Haoliang Xue, Sifei Zhou, Weimin Yang
Summary: In this study, a new design for high-performance lithium-sulfur (Li-S) battery separator modifiers is proposed. By constructing a metallic cobalt-doped ZSM-5 zeolite with extra-framework Li+, the migration of polysulfides is effectively inhibited and their conversion kinetics are enhanced, resulting in long-term cyclic stability and excellent rate capability of Li-S batteries.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Xiaoshi Lang, Ruiyin Ren, Xinxi Wang, Lan Li, Kedi Cai
Summary: Cu2+ regulated Fe2O3 nanospheres were prepared as high-performance matrixes for sulfur composite cathodes of lithium-sulfur batteries via a facile hydrothermal method, effectively solving the issues of sulfur insulation, volume alternation, and shuttle effect.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Baoying Dang, Quanqing Li, Yuhong Luo, Ruohan Zhao, Jingde Li, Feichao Wu
Summary: A composite membrane consisting of metal-organic framework and glass fiber membrane is proposed to address the issues of polysulfide shuttle and lithium dendrite growth in lithium-sulfur batteries. The membrane is capable of simultaneously resolving these two problems.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Yuanchun Ji, Xinyang Liu-Theato, Yanlei Xiu, Sylvio Indris, Christian Njel, Julia Maibach, Helmut Ehrenberg, Maximilian Fichtner, Zhirong Zhao-Karger
Summary: The magnesium-sulfur (Mg-S) battery is considered a promising candidate for post-lithium battery systems due to its high energy density, safety, and cost effectiveness. However, issues such as the shuttle effect of soluble polysulfides have hindered the realization of sulfur-based battery technology. This study investigates the use of a glass fiber separator coated with decavanadate-based polyoxometalate (POM) clusters/carbon composite to improve battery performance and suppress polysulfide shuttling, resulting in enhanced reversible capacity and cycling stability in Mg-S batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Polymer Science
Hyukmin Kweon, William Kim-Shoemaker
Summary: This study applied a conductive, flexible, and easily modified polymer composite layer in lithium sulfur batteries to mitigate lithium dissolution and polysulfide shuttle effect. The results showed that the polymer composite layer reduced the amount of lithium polysulfide species and dissolved lithium ions in the batteries.
Article
Chemistry, Physical
Binbin Yang, Shuixin Xia, Hao Sun, Xun Zhang, Yuepeng Pang, Junhe Yang, Shiyou Zheng
Summary: By utilizing layered-double-hydroxide ultrathin nanosheet (LUN)-decorated Celgard separators, this research successfully addresses issues such as lithium polysulfide shuttle and dendritic Li growth, significantly improving the cycle life and stability of lithium-sulfur batteries.
ACS APPLIED ENERGY MATERIALS
(2021)
Review
Polymer Science
Yingbao Zhu, Zhou Chen, Hui Chen, Xuguang Fu, Desire Emefa Awuye, Xichen Yin, Yixuan Zhao
Summary: Lithium-sulfur (Li-S) batteries have high theoretical capacity, high theoretical capacity density, and low cost, making them a promising energy storage system. However, challenges such as poor sulfur conductivity, the shuttle effect caused by lithium polysulfide, and lithium dendrite growth hinder the commercial development of Li-S batteries. The separator, as a crucial component, plays a vital role in mitigating the shuttle effect. This review summarizes the applications of various separator preparation and modification methods in Li-S batteries and analyzes their electrochemical performance.
Article
Nanoscience & Nanotechnology
Pui Lap Jacob Lee, Vigneshwaran Thangavel, Claude Guery, Christina Trautmann, Maria Eugenia Toimil-Molares, Mathieu Morcrette
Summary: This study explores the use of polymer etched ion-track membranes as separators in Li-S batteries to mitigate the redox shuttle effect. Compared to commercial separators, these membranes offer unique advantages in adjusting and optimizing the density, geometry, and diameter of nanopores, effectively reducing the self-discharge issue of the battery.
Article
Chemistry, Multidisciplinary
Yuanyuan Li, Qing Yan, Juan Zhu, Yongyuan Ren, Quan Liu, Yang Hou, Jianguo Lu, Xiang Gao, Xiaoli Zhan, Qinghua Zhang
Summary: A rational design of vertical MoS2 nanosheets anchored on carbon nanotubes is proposed to inhibit the shuttle effect of polysulfides and improve the cycling stability and electrochemical performance of lithium sulfur batteries.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Yun Guo, Peisen Wu, Hao Zhong, Jianlin Huang, Guozheng Ma, Zhiguang Xu, Yongbo Wu, Akif Zeb, Xiaoming Lin
Summary: Lithium sulfur batteries are replacing conventional lithium-ion batteries due to their high theoretical capacity, low cost, and non-toxicity. Functionalized carbon materials used as modifier layers on the separator have been found to catalyze the breakdown of polysulfides, improving the efficiency of lithium sulfur batteries.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Xinyuan Jiang, Zhen Wu, Suqin Duan, Yi Liu, Zhiyuan Ma, Hangyu Zhang, Lubin Ni, Yongge Wei
Summary: This paper presents the use of polyvinylidene fluoride with polar functional groups as a carrier, and the electrospinning technique to construct H3PW12O40 nanofibers membrane, addressing the issues of capacity degradation and poor cycling stability caused by polysulfide intermediates in lithium-sulfur batteries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Chemical
Wenyi Zhu, Zhijia Zhang, Jiankun Wei, Yidan Jing, Wei Guo, Zhizhong Xie, Deyu Qu, Dan Liu, Haolin Tang, Junsheng Li
JOURNAL OF MEMBRANE SCIENCE
(2020)
Article
Chemistry, Physical
Kan Fang, Dan Liu, Xinyuan Xiang, Xinxin Zhu, Haolin Tang, Deyu Qu, Zhizhong Xie, Junsheng Li, Deyang Qu
Article
Chemistry, Physical
Hao Li, Dan Liu, Xinxin Zhu, Deyu Qu, Zhizhong Xie, Junsheng Li, Haolin Tang, Dong Zheng, Deyang Qu
Review
Materials Science, Multidisciplinary
Min Wei, Xi Pan, Lin Rong, Aijun Dong, Yunlu He, Xuyan Song, Junsheng Li
MATERIALS RESEARCH EXPRESS
(2020)
Article
Electrochemistry
Lu Wang, Xinxin Zhu, Keke Tu, Dan Liu, Haolin Tang, Junsheng Li, Xi Li, Zhi-zhong Xie, Deyu Qu
ELECTROCHIMICA ACTA
(2020)
Article
Chemistry, Multidisciplinary
Liuli Zeng, Zhijia Zhang, Weijian Qiu, Jiankun Wei, Zhihuang Fang, Qibo Deng, Wei Guo, Dan Liu, Zhizhong Xie, Deyu Qu, Haolin Tang, Junsheng Li, Ning Hu
Article
Energy & Fuels
Hui He, Xiaoduo Xu, Dan Liu, Jing Li, Yuhui Wei, Haolin Tang, Junsheng Li, Xi Li, Zhi-Zhong Xie, Deyu Qu
Summary: Nitrogen-doped activated carbon materials show excellent hydrogen storage performance, with high hydrogen storage capacity and retention rate. The main nitrogen functional groups include pyrrole N, pyridine N oxide, and nitro N.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Physical
Ke Li, Jun Xu, Chan Chen, Zhizhog Xie, Dan Liu, Deyu Qu, Haolin Tang, Qiang Wei, Qibo Deng, Junsheng Li, Ning Hu
Summary: The study suggests enhancing the intrinsic electrocatalytic activity of Pt and reducing the amount of Pt in the catalyst by introducing a synergistic interaction with NiS2. This strategy was proven effective through experimental and theoretical investigations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Review
Chemistry, Applied
Zhijia Zhang, Zhihuang Fang, Yinyu Xiang, Dan Liu, Zhizhong Xie, Deyu Qu, Meiling Sun, Haolin Tang, Junsheng Li
Summary: Cellulose-based materials have shown promising applications in Li-S batteries as separator, carbon materials for binder assisted modification, and carbon hosts for sulfur cathode. Despite the challenges, there is potential for further development and utilization of cellulose-based materials in Li-S batteries.
CARBOHYDRATE POLYMERS
(2021)
Article
Electrochemistry
Jiankun Wei, Yidan Jing, Zelin Zhao, Zhengwen Fan, Zijia Liang, Junling Huang, Han Wu, Zhizhong Xie, Dan Liu, Deyu Qu, Haolin Tang, Junsheng Li
Summary: The study suggests a strategy to enhance the performance of ENRR catalyst through catalyst support interactions, which is verified experimentally. The transfer of electrons from the ZrO2 substrate to Au modifies the electronic structure of Au, enhancing the catalyst's activity.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Xuyan Song, Min Wei, Xi Pan, Yunlu He, Xinjiao Cui, Xiaodi Du, Junsheng Li
Summary: Investigating the mechanism of eugenol release from tobacco leaf as the model substrate, it was found to be a temperature-dependent process closely associated with the morphology change of tobacco leaves under heating conditions. This insight may be useful for the future design of fragrance release systems.
APPLIED SCIENCES-BASEL
(2021)
Article
Chemistry, Multidisciplinary
Xuyan Song, Min Wei, Yunlu He, Xi Pan, Xinjiao Cui, Xiaodi Du, Junsheng Li
Summary: The study introduces a low-cost alternative to the standard Cambridge filter pad (CFP) for capturing particulate matter in mainstream smoke. The alternative filter is composed of a cellulose acetate fiber (CAF) interlayer and two cotton fiber (CF) layers, showing improved trapping performance and high affinity towards tobacco additives. This cost-effective CF/CAF/CF filter can potentially replace the CFP.
APPLIED SCIENCES-BASEL
(2022)
Article
Biochemistry & Molecular Biology
Xinjiao Cui, Donghao Ye, Jiankun Wei, Xiaodi Du, Pengzhao Wang, Junsheng Li
Summary: This research developed a novel composite fragrance carrier with MIL-101 (Cr) as the fragrance host and cellulose acetate fiber (CAF) as the protective shell. The encapsulation effect of MIL-101 (Cr) and the protective function of the CAF shell significantly improved the storage stability of fragrance and enabled thermal triggered release.
Review
Biochemistry & Molecular Biology
Zijie Luo, Jia Wang, Wei Zhou, Junsheng Li
Summary: In the context of growing demand for green secondary energy sources, the development of stable, efficient, and low-cost oxygen evolution reaction (OER) catalysts is crucial for proton-exchange membrane water electrolysis (PEMWE) to produce high-purity hydrogen for proton-exchange membrane fuel cells (PEMFCs). Precious metals remain irreplaceable in acidic OER catalysis, and loading the support body with precious metal components is an effective strategy to reduce costs. This review discusses the role of common catalyst-support interactions in modulating catalyst structure and performance, promoting the development of high-performance, high-stability, low-cost noble metal-based acidic OER catalysts.
Article
Nanoscience & Nanotechnology
Mengjun Wu, Dan Liu, Deyu Qu, Zhizhong Xie, Junsheng Li, Jiaheng Lei, Haolin Tang
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Engineering, Chemical
Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu
Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Retraction
Engineering, Chemical
Chang Liu, Jinghong Liu, Liang Zhu, Shanfu Tang, Huixin Xiong
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma
Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman
Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer
Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho
Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang
Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar
Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev
Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun
Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li
Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis
Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang
Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes
Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang
Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.
JOURNAL OF MEMBRANE SCIENCE
(2024)