期刊
JOURNAL OF CATALYSIS
卷 360, 期 -, 页码 270-276出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.02.018
关键词
Silver ferrite; Delafossite; Fluorination; Carboxylic acids; Heterogeneous catalyst
资金
- Vietnam National Foundation for Science and Technology Development (NAFOSTED) [104.01-2014.76]
A crystalline delafossite of silver ferrite AgFeO2 nanoparticles were successfully synthesized by modified method. Physical characterizations of the AgFeO2 catalyst were obtained by several techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray Fluorescence (XRF), and nitrogen physisorption measurements. The material was applied as active heterogeneous catalyst for decarboxylative fluorination of carboxylic acids. The optimized conditions utilized the electrophilic Selectfluor reagent in acetone/H2O solvent at room temperature in 3 h. Investigation of structure/activity relationship revealed strong synergistic effect of iron on silver center. Subsequently, AgFeO2 showed remarkable higher activity than homogeneous silver salts, other metal oxides and common Ag-based heterogeneous catalysts. Leaching test indicated the exceptional stability of AgFeO2 structure as compared to other heterogeneous systems and the contribution of leached species is unlikely. Subsequently, AgFeO2 could be reused for at least 7 runs without significant degradation in activity. (C) 2018 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据