期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 135, 期 37, 页码 -出版社
WILEY
DOI: 10.1002/app.46685
关键词
batteries and fuel cells; electrochemistry; fullerenes; graphene; nanotubes
资金
- Iran Ministry of Science, Research, and Technology
- Science and Innovation Spanish Ministry [DPI2013-046541-R, TIN2014-56967-R, TEC2016-80700-R]
- FEDER [DPI2013-046541-R, TIN2014-56967-R, TEC2016-80700-R]
- Principality of Asturias Government [FC-15-GRUPIN14-073]
- Spanish Ministry of Economy and Competitiveness [CTQ2014-58989-P, CTQ2015-71936-REDT]
An exhaustive study on a nanocomposite-poly(methyl methacrylate) matrix material as a supercapacitor is presented. The study includes morphological, structural, and electrochemical characterization. Different electrolytes were used, for which both pseudocapacitance (for reduced graphene oxide) and electric double-layer capacitance (for functionalized graphene) were observed. An optimum nanocomposite weight percentage was found (2%), and the best performance with highest capacitance (30.4 F/g) was seen for the electrolyte including the smallest anions (OH-), being among the best values for similar systems, that is, a nanocomposite/nonconductive polymer matrix. In addition, a model is presented that explains the underlying electron transport mechanism. The results are promising for the construction of supercapacitors based on novel nanocomposite-poly(methyl methacrylate) matrix materials. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46685
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