期刊
JOURNAL OF APPLIED PHYSICS
卷 124, 期 3, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5034390
关键词
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资金
- Japan Society for the Promotion of Science [17K06771]
- Grants-in-Aid for Scientific Research [17K06771] Funding Source: KAKEN
Heusler-type Fe(2)VAI thermoelectric materials have been processed by high-pressure torsion (HPT) to improve their thermoelectric performance through a drastic reduction of the thermal conductivity. While the thermal conductivity for Fe(2)VTa(0.05)A(10)(.95) is about 10 W/m K at 300 K, it is reduced to about 5.0 W/m K due to HPT processing. Furthermore, even after annealing at 873 K for recurrence of the Heusler-type structure, Ta-doped Fe(2)VTa(0.05)A(10.95) possesses an ultra-fine grained structure with an average grain size of about 80 nm, in contrast to the presence of large grains of about 270 nm for non-doped Fe(2)V(1.05)A(10.95). Since scanning transmission electron microscopy combined with energy-dispersive X-ray analysis reveals the solute segregation of Ta along grain boundaries and recrystallization interfaces, the retardation of recrystallization could be caused by the solute drag effect, leading to a suppression of grain coarsening. Thus, it is possible to retain the low thermal conductivity of about 5.0 W/m K at 300 K for Fe(2)VTa(0.05)A(10.95), in parallel with the restoration of a large power factor, so that the dimensionless figure of merit reaches ZT = 0.30 at around 500 K. Published by AIP Publishing.
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