4.7 Article

Hollow ZnS submicrospheres encapsulated in carbon shells with enhanced lithium and sodium storage properties

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 735, 期 -, 页码 51-61

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.11.046

关键词

Hollow zinc sulfide; Carbon coating; Anode materials; Lithium-ion batteries; Sodium-ion batteries

资金

  1. National Natural Science Foundation of China [51672213, 21601144]
  2. key project of Research and Development of Shaanxi Province [2017ZDCXL-GY-08-01]
  3. Key Science and Technology Innovation Team Project of Natural Science Foundation of Shaanxi Province [2017KCT-01]
  4. Natural Science Foundation of Shaanxi Province [2017JM2025]
  5. Xi'an Science and Technology Project- Engineering Program of University and Institute Talents Servicing Enterprise [2017085CG/RC048(XBDX005)]

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A hybrid material consisting of hollow ZnS submicrospheres encapsulated in carbon shells (HeZnS@C) was synthesized by a simple two-step hydrothermal route followed by a subsequent calcination process using zinc acetate, thiourea, and glucose as raw materials. The morphological and structural characterizations indicated that HeZnS@C hybrid particles 200 nm in diameter coated by a carbon layer measuring 2 nm in thickness was prepared from the synthesis process. The electrochemical properties of the hybrid as an anode material for lithium-ion batteries and sodium-ion batteries were investigated. Electrochemical tests demonstrated that the HeZnS@C hybrid could deliver an enhanced lithium/sodium storage performance, including a better specific capacity, cycling stability, and rate capability compared to HeZnS. The reasons for the excellent energy storage performance of HeZnS@C were investigated and discussed. (C) 2017 Elsevier B.V. All rights reserved.

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