4.7 Article

A mesoporous metal-organic framework: Potential advances in selective dye adsorption

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 750, 期 -, 页码 360-367

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2018.03.393

关键词

Metal-organic frameworks; Mesoporous; Dyes; Selective adsorption

资金

  1. National Natural Science Foundation of China [21601048, 21671055]
  2. China Post-doctoral Science Foundation [2015M580626]
  3. Natural Science Foundation Project of Henan province [162102210171, 162300410012]
  4. State Key Laboratory of Fine Chemicals [KF1602]

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A new metal-organic framework based on manganous (II) ions and a paddle wheel ligand, H-3[Mn3O3(BTB)] (Mn-BTB, HBTB = 1,3,5-tris(4-carboxyphenyl)benzene acid), was synthesized and structurally characterized. Mn-BTB was formed via self-assembly of one-dimensional (1D) helical chains interconnected through the carboxyl groups of the tripodal ligand HBTB to generate a 3D, extended network with a nanotube-like architecture and aperture size of 18.22 angstrom x 16.40 angstrom. The 2-fold self-interpenetration significantly enhanced the stability of the framework, although it minimized the empty space to some extent. Mn-BTB contains an accessible volume of 3143.6 angstrom(3) with a 47.1% porosity, which allowed the adsorption of large dye molecules. Cationic dyes (methylene blue (MB) and rhodamine B (RhB)) and an anionic dye (methyl orange (MO)) were examined for selective dye adsorption on Mn-BTB. Mn-BTB with an anionic skeleton was beneficial for the selective adsorption of cationic dyes. (C) 2018 Elsevier B.V. All rights reserved.

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