4.7 Article

Fabrication of Co3V2O7(OH)2 center dot 2H(2)O hexagonal microplatelets and its application in lithium-ion batteries

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 735, 期 -, 页码 700-706

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2017.11.177

关键词

Cobalt vanadates; Functional; Lithium-ion batteries; Electrochemical properties; Anode materials

资金

  1. National Natural Science Foundation of China [21303107]
  2. Natural Science Foundation of Hebei Province [B2014106056]
  3. Program of Hundred Innovative Talents of Higher Education Institutions of Hebei Province [BR2-264]
  4. Scientific Research Platform of Shijiazhuang University [2013]

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Co3V2O7(OH)(2)center dot 2H(2)O hexagonal microplatelets with the thickness of 1-2 mu m and the diameter of 15 -20 mu m have been successfully prepared on a large scale via a hydrothermal process without using any templates or surfactants. Electrochemical evaluation revealed that the as-prepared Co3V2O7(OH)(2)center dot 2H(2)O hexagonal microplatelets exhibited high discharge capacity and good cyclability. The reversible capacity of 288.1 mA h g(-1) was delivered after 50 cycles at a current density of 50 mA g(-1), with Coulombic efficiency of about 98%. The present work will greatly expand the range of the anode materials choices for lithium-ion batteries. (C) 2017 Elsevier B.V. All rights reserved.

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