Article
Materials Science, Ceramics
Lin Zhao, Kui Chen, Jian Ma, Hong Tao, Wenjuan Wu, Chunlin Zhao, Bo Wu
Summary: The development of lead-free (K, Na)NbO3(KNN)-based materials with excellent piezoelectric properties is important due to their environmental friendliness and potential for device applications. This study focuses on the exploration of the electrostrictive effect potential in KNN-based piezoelectric materials, specifically (1-x)K0.5Na0.5NbO3-xBi0.5Na0.5ZrO3 (KNN-xBNZ), by enhancing the relaxor characteristic through introducing a high content of BNZ. The optimized KNN-0.1BNZ material shows a giant electrostrictive coefficient (Q(33)) nearly three times higher than reported Pb(Zr, Ti)O-3-based materials and has a pretty frequency stability, enabling its application in commercial fuel injectors' actuators. This research provides a high-performance electrostrictive material and promotes the research of eco-friendly piezoelectric materials.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Fangfang Zeng, Jianjia Zhang, Chuang Zhou, Lei Jiang, Huitao Guo, Yuxin Chen, Wenzhong Lu, Haibo Zhang, Wei Cai, Yongming Hu, Guifen Fan
Summary: This study successfully prepared a high-temperature piezoelectric material with excellent thermal stability, and the outstanding piezoelectric performance is mainly attributed to the combination of freezing temperature and polar nanoregions.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Materials Science, Ceramics
Leiyang Zhang, Ruiyi Jing, Yunyao Huang, Qingyuan Hu, D. O. Alikin, V. Ya Shur, Dawei Wang, Xiaoyong Wei, Lin Zhang, Gang Liu, Li Jin
Summary: This research clarifies the electrostrictive effect in KNN-based systems, demonstrating that the Q(33) values in the KNLN-ST system fall within a reasonable range for perovskite-structured ferroelectric ceramics. Furthermore, an ultra-high electrostrictive strain was achieved in the 0.8KNLN-0.2ST sample, expanding the potential application field of KNN-based ceramics to electrostrictive actuators.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Ceramics
Fangbin Wei, Yule Yang, Leiyang Zhang, Denis Alikin, Vladimir Shur, Amei Zhang, Hongliang Du, Xiaoyong Wei, Li Jin
Summary: High recoverable energy storage density (W-rec) and high energy storage efficiency (eta) are urgently needed for their potential application in pulse capacitor devices. However, low eta and breakdown strength (BDS) have hindered the achievement of high W-rec at high electric field. In this study, Bi(Mg0.5Ti0.5)O-3 (BMT) was introduced into Ba(Ti0.92Sn0.08)O-3 (BTS) matrix to enhance the relaxor character and reduce electrostrictive strain. The results showed significantly improved BDS and a high W-rec of 4.34 J/cm(3) with excellent temperature stability.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Tianqiong Wu, Wu Zhang, Fafu Liu, Zhanmin Dou, Shengqiang Han, Pengyuan Fan, Sheng-Gui Chen, Chanatip Samart, David Salamon, Hua Tan, Haibo Zhang
Summary: In this research, the introduction of 0.93NBT-0.07BT ceramic into 0.7BF-0.3BT ceramic has enhanced the piezoelectric property by creating a morphotropic phase boundary. XRD analysis confirms the presence of a homogeneous solid solution in the (0.7BF-0.3BT)-x(0.93NBT-0.07BT) ceramics, still within the MPB region. This study provides a new approach for the application of BF-BT ceramics in high-temperature piezoelectric devices.
CERAMICS INTERNATIONAL
(2023)
Article
Engineering, Environmental
Zhi-Gang Liu, Ming-Ding Li, Zhen-Hua Tang, Xin-Gui Tang
Summary: Composite energy storage ceramics (BT-BMH) were prepared for the first time using the traditional solid-state method, showing significant relaxation behaviors and improved energy storage performance. The addition of BMH induced relaxor ferroelectric properties and resulted in sublinear hysteresis loops in the ceramics, facilitating efficient energy storage. The optimized BT-BMH ceramics demonstrated excellent stability at variable temperatures and frequencies, indicating potential for energy storage applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Ceramics
Yanela Mendez-Gonzalez, Anthony Ferri, Elton C. Lima, Ahmad Hamieh, Denis Remiens, Aime Pelaiz-Barranco, Atair C. Silva, Jose de los Santos Guerra
Summary: The structural, microstructural, and electromechanical properties of lead-free BNLBT-x thin films were investigated as a function of lanthanum concentration. The increased lanthanum content led to a decrease in grain size and surface roughness, while also revealing distinct ferroelectric domain structures and the presence of antiferroelectric phases on the surface. The materials showed potential for integration into advanced electronic nanodevices, with reliable switching behavior and noticeable piezoactivity increasing with higher doping content.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
Thi Hinh Dinh, Jae-Shin Lee
Summary: An investigation on ternary lead-free Na0.5Bi0.5TiO3-SrTiO3-ABO(3) piezoceramics reveals that the addition of ABO(3) affects the phase transition temperature and ferroelectric order of the materials. Microwave sintering method shows potential for creating lead-free piezoactuator materials with high performance.
Article
Materials Science, Ceramics
Leiyang Zhang, Yang Yang, Hongping Hou, Amei Zhang, Zhuang Miao, Jia Liu, Xin Wang, Yudong Hou, Hongliang Du, Li Jin
Summary: This study focuses on the development of <001>-oriented BCZT ceramics with a high Q(33) value and excellent performance stability, achieved through the use of template grain growth method. These ceramics exhibit a significant increase in Q(33) compared to randomly oriented ceramics, and also demonstrate ultra-high electrostrictive strain response and minimal hysteresis. The elevated Q(33) remains thermally stable, making it suitable for high-precision actuator technologies.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Anping Deng, Jiagang Wu
Summary: Rare earth ion doping has a significant effect on the phase structure, microstructure, strain, and electrostrictive properties of lead-free BNT-based ceramics. Moderate La3+ ion doping can drive the ceramics to nonergodic or ergodic relaxor states, resulting in enhanced strain response and high converse piezoelectric coefficient.
JOURNAL OF MATERIOMICS
(2022)
Article
Engineering, Electrical & Electronic
Mauro Difeo, Fernando Rubio-Marcos, Adolfo Del Campo, Miriam Castro, Leandro Ramajo
Summary: Sodium bismuth titanate based lead-free piezoceramics with modified dielectric and energy storage properties were obtained by doping Nb. The doping of Nb changes the material structure and microstructural characteristics, resulting in a transition from multiphasic coexistence to a single phase, and improving the piezoelectric response and energy storage properties of the material.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Materials Science, Ceramics
Xianya Wang, Xinyu Liu, Haoyue Xue, Jie Yin, Jiagang Wu
Summary: Rarely studied dopant Sb is found to effectively overcome the drawbacks of high hysteresis and poor temperature stability in BNT-based piezoelectric ceramics, showing excellent electro-strain behavior over a wide temperature range of 40-120 degrees Celsius. This suggests that Sb-modified BNT-based ceramics have higher potential for practical actuator applications compared to previously reported materials.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Xiang He, Muzaffar Ahmad Boda, Chen Chen, Rongmin Dun, Lu Wang, Yizheng Bao, Dongfang Pang, Lin Guo, Huarong Zeng, Yongxiang Li, Zhiguo Yi
Summary: A universal strategy to enable large electromechanical deformations in various piezoceramics is still lacking. In this study, by gradually reducing the thickness, it was discovered that thin lead-free piezoceramics can achieve large electrostrain, and the bending deformation induced by asymmetric domain switching in the surface layers plays a significant role in the enhanced strain output and shape retention effect. These findings have the potential to accelerate the development of high-performance lead-free piezoceramics.
MATERIALS HORIZONS
(2023)
Article
Multidisciplinary Sciences
Chao-Ran Huang, Xuzhong Luo, Xiao-Gang Chen, Xian-Jiang Song, Zhi-Xu Zhang, Ren-Gen Xiong
Summary: The study introduces the first lead-free 2D HOIP multiaxial ferroelectric, which displays more ferroelectric axes and equivalent polarization directions than other 2D HOIP ferroelectrics and lead-free inorganic perovskite BaTiO3. The new material features a high Curie temperature and remarkable thermochromism, offering a new direction for the development of lead-free 2D HOIP ferroelectrics.
NATIONAL SCIENCE REVIEW
(2021)
Article
Chemistry, Physical
Peng Shi, Tangyuan Li, Xiaojie Lou, Zhonghai Yu, Xiaopei Zhu, Chao Zhou, Qida Liu, Liqiang He, Xiaoxiao Zhang, Sen Yang
Summary: The study found that BNT-9(BCT-BZT) ceramics exhibit a large field-induced strain of 0.42% and large reverse piezoelectric coefficient of 547 pm/V; while BNT-10(BCT-BZT) ceramics show a large recoverable energy storage of 3.49 J/cm(3) and high energy storage efficiency of 64.9%. These ceramics are believed to be favorable for practical applications in mobile electronic devices.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Qingyuan Hu, Huimin Liao, Xin Liu, Li Jin, Kexin Song, Yongyong Zhuang, Zhuo Xu, Vladimir Ya Shur, Xiaoyong Wei
Summary: In this study, a thermal annealing and high temperature poling approach is proposed to enhance the piezoelectricity of Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 crystals. The manipulation of defects and defect polarization orientation results in a more polarized crystal. The improved piezoelectric property achieved under a maintained Curie temperature indicates the feasibility of the approach.
JOURNAL OF MATERIOMICS
(2023)
Article
Materials Science, Ceramics
Fangbin Wei, Yule Yang, Leiyang Zhang, Denis Alikin, Vladimir Shur, Amei Zhang, Hongliang Du, Xiaoyong Wei, Li Jin
Summary: High recoverable energy storage density (W-rec) and high energy storage efficiency (eta) are urgently needed for their potential application in pulse capacitor devices. However, low eta and breakdown strength (BDS) have hindered the achievement of high W-rec at high electric field. In this study, Bi(Mg0.5Ti0.5)O-3 (BMT) was introduced into Ba(Ti0.92Sn0.08)O-3 (BTS) matrix to enhance the relaxor character and reduce electrostrictive strain. The results showed significantly improved BDS and a high W-rec of 4.34 J/cm(3) with excellent temperature stability.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Wen-Jing Shi, Lei-Yang Zhang, Yu-Le Yang, D. O. Alikin, V. Ya. Shur, Xiao-Yong Wei, Hong-Liang Du, Li Jin
Summary: Lead-free dielectric ceramics with improved energy storage performance (ESP) were developed using a combinatorial optimization strategy. By introducing Bi-containing complex ions and employing a viscous polymer process, the ceramics exhibited enhanced diffuse phase transition, increased bond coupling, and reduced hysteresis. The optimized composition achieved high recoverable energy storage density (W-rec), high efficiency, and remarkable temperature stability for pulsed power capacitors.
Article
Chemistry, Physical
Wen Wang, Leiyang Zhang, Yule Yang, Wenjing Shi, Yunyao Huang, D. O. Alikin, V. Ya. Shur, Zhihao Lou, Amei Zhang, Xiaoyong Wei, Dong Wang, Feng Gao, Hongliang Du, Li Jin
Summary: This study achieved comprehensive exceptional energy storage performance in Na0.5Bi0.5TiO3-Sr0.85Bi0.1TiO3 (NBT-SBT)-based ceramics through stepwise optimization by substituting Bi(Mg0.5Sn0.5)O-3 (BMS) and optimizing the formation process. The introduction of Mg2+ and Sn4+ ions at the B-site induced polar nanoregions, and the viscous polymer process (VPP) improved the polarization difference and breakdown strength. As a result, the ceramics exhibited ultrahigh energy storage density and high efficiency, along with excellent temperature adaptability.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Materials Science, Ceramics
Gang Liu, Huanghui Nie, Leiyang Zhang, Xinyu Zeng, Yazhong Zheng, Xinyu Chen, Xinran Wang, Kun Yu, Li Jin, Yan Yan
Summary: In the past decade, there has been a great deal of attention on acquiring giant electric field-induced strain in non-Pb materials. In this study, the crystal and domain structures, as well as the electrical performances of (1-x) (0.94Bi0.5Na0.5TiO3-0.06BaTiO3)-xNaTaO3 (BNBT-xNT) specimens, were systematically studied to achieve enhanced strain. The introduction of NT resulted in a phase structure transition from rhombohedral-tetragonal to pseudo-cubic structure, causing the destruction of the original domain structure of BNBT and an increase in the disorder degree of the local structure. Simultaneously, the remnant polarization, coercive field, and piezoelectric coefficients were significantly decreased. The BNBT-3NT ceramics achieved marked strain coefficients at room temperature, with a maximum strain of 0.394% under 65 kV/cm and a d33* of 606 pm/V.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Tao Deng, Yilin Zhang, Xinyu Zeng, Fukang Chen, Yan Yan, Yang Li, Mingyang Tang, Leiyang Zhang, Li Jin, Gang Liu
Summary: A composition embellishment and process improvement strategy were adopted to acquire electric capacitors with enhanced energy storing performance. A series of lead-free (Ba0.875Bi0.125)(Li0.0625Nb0.0625Ti0.875)O3(BBLNT) ceramics were prepared using both the conventional solid-state method and viscous polymer processing technology (VPP). The BBLNT-VPP ceramics achieved an ultrahigh energy storing density of 5.34 J/cm3 and a reasonable efficiency of 88% at 470 kV/cm. The ceramics also exhibited extraordinary temperature stability and excellent frequency stability.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Xiyu Ma, Wenjing Shi, Yule Yang, D. O. Alikin, Y. Ya Shur, Jinghui Gao, Xiaoyong Wei, Gang Liu, Hongliang Du, Li Jin
Summary: Electrocaloric refrigeration is an emerging solid-state technology with advantages of high efficiency, miniaturization, eco-friendliness, and low cost. This paper investigates Ba(Ti1-xSnx)O-3 ceramics and reveals their structural, dielectric, ferroelectric, electrocaloric, and electrostrictive characteristics. The results show that increasing Sn4+ concentration leads to lower dielectric peaks and a phase diagram is constructed based on dielectric characteristics. The study also demonstrates a giant adiabatic temperature change of 6.36 K in the x = 0.04 ceramic sample and temperature and composition-insensitive electrostrictive behavior.
CERAMICS INTERNATIONAL
(2023)
Article
Engineering, Environmental
Leiyang Zhang, Mo Zhao, Yule Yang, Yang Li, Mingyang Tang, Dong Wang, Xiaoyong Wei, Gang Liu, Yan Yan, Li Jin
Summary: This article introduces a novel method to regulate polar nanoregions (PNRs), aiming to achieve both ultra-high recovered energy density (Wrec) and ultra-high efficiency (eta) in (Na0.5Bi0.5)TiO3 (NBT)-based relaxor ferroelectric ceramics. The study provides insights for developing alternative lead-free dielectric ceramic materials.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Jingrui Kang, Xu Guo, Rui Gu, Yi Tang, Honglei Hao, Yu Lan, Li Jin, Xiaoyong Wei
Summary: In this study, boron-based glass additives (B2O3, B2O3-SiO2-PbO (BSP), and B2O3- SiO2-K2O-Al2O3 (BSKA)) were successfully added to LATP by solid method, which effectively improved its density and ionic resistance. The addition of boron-based glass promoted the grain growth of LATP and increased its relative density, while reducing the activation energy and enhancing the total conductivity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Tong Wang, Leyan Zhang, Aoyu Zhang, Jiaxiang Liu, Luo Kong, Guanjun Chen, Yan Cheng, Ye Tian, Haibo Yang, Yongming Hu, Zhuo Xing, Chunchun Li, Li Jin
Summary: The NBT-KBT-KNN ceramic solid solution was synthesized by solid phase method with different KNN content. XRD, Raman, and SEM results confirmed the formation of solid solutions with a stable perovskite structure. The addition of KNN enhanced the relaxor ferro-electrics properties and improved the energy storage performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Qingyuan Hu, Denis Alikin, Boris Slautin, Anton Turygin, Xin Liu, Pengfei Li, Yuebin Zhang, Dabin Lin, Kexin Song, Yongyong Zhuang, Zhuo Xu, Pavel Zelenovskiy, Vladimir. Ya. Shur, Xiaoyong Wei
Summary: The domain structure and surface screening charges during phase transitions in the (001) oriented 0.72PMN-0.28PT crystal were investigated at the nanoscale using piezo-response force microscopy (PFM) and Kelvin probe force microscopy (KPFM). Electric field induced phase transitions were studied locally with confocal polarized Raman spectroscopy. It was found that PFM tip bias poling can induce a rhombohedral to monoclinic phase transition in the 0.72PMN-0.28PT single crystal, and the monoclinic phase relaxes back to the rhombohedral phase at elevated temperatures. This study provides valuable insights into the electric field induced phase transition and its practical applications for PMN-PT single crystals.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
Yongxing Wei, Huawei Zhang, Siyuan Dong, Changqing Jin, Chenxing Bai, Junle Dai, Zengzhe Xi, Zhonghua Dai, Zengyun Jian, Li Jin
Summary: In this study, solid solutions of xBi(Ni1/2Hf1/2)O-3-(1 - x)PbTiO3 (xBNH-PT) were synthesized to investigate their phase boundary behaviors and physical properties. The presence of a tetragonal-pseudocubic phase boundary and a spontaneous ferroelectric-relaxor transition at specific compositions were confirmed. The introduction of a tetragonal-pseudocubic phase boundary improved the piezoelectric properties and suppressed the spontaneous ferroelectric-relaxor transition.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)