4.7 Article

Tripodal N,P Mixed-Donor Ligands and Their Cobalt Complexes: Efficient Catalysts for Acceptorless Dehydrogenation of Secondary Alcohols

期刊

INORGANIC CHEMISTRY
卷 57, 期 5, 页码 2394-2397

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AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b00043

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资金

  1. National Science Foundation (NSF-RUI) [CHE-1465051]
  2. ACS Project SEED scholarship
  3. FRCAC
  4. URECA
  5. MTSU
  6. NSF-MRI [CHE-1626549]
  7. Division Of Chemistry
  8. Direct For Mathematical & Physical Scien [1626549] Funding Source: National Science Foundation

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A new tetradentate tripodal ligand, (PPPNPyMe)-P-iPr-Py-H, and the cobalt complexes were synthesized and characterized. The well-defined cobalt complexes efficiently catalyzed acceptorless dehydrogenation of secondary alcohols into ketones.

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