期刊
INORGANIC CHEMISTRY
卷 57, 期 9, 页码 4828-4832出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b00702
关键词
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资金
- National Natural Science Foundation of China [21671175, 21371153]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
- Zhengzhou University
A polyoxometalate-templated silver(I) thiolate nanocluster has been synthesized by a one-pot reaction in high yield. This novel and stable nanocluster exhibits a core-shell structure with a Ag67S36 shell and two lacunary Keggin [PW9O34](9-) cores, which is fully characterized by X-ray crystallography, X-ray photoelectron spectroscopy, UV-vis, powder X-ray diffraction, and cyclic voltammetry.
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